Fabrication of a Cu2ZnSn(S,Se)4 Photovoltaic Device by a Low-Toxicity Ethanol Solution Process

被引：136

作者：

Wang, Gang ^{[1
]}

Zhao, Wangen ^{[1
]}

Cui, Yong ^{[1
]}

Tian, Qingwen ^{[1
]}

Gao, Shang ^{[1
]}

Huang, Lijian ^{[1
]}

Pan, Daocheng ^{[1
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Jilin, Peoples R China

来源：

ACS APPLIED MATERIALS & INTERFACES | 2013年 / 5卷 / 20期

基金：

中国国家自然科学基金;

关键词：

CZTSSe; kesterite; thin film; solar cells; solution process; FILM SOLAR-CELLS; THIN-FILM; PRECURSOR SOLUTION; CU2ZNSNS4; EFFICIENCY; DEPOSITION; BINARY; SULFUR;

D O I：

10.1021/am402558a

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Homogeneous molecular precursor solutions are excellent choices for obtaining smooth absorber layers, and they offer the potential to significantly lower the manufacturing cost of solar cells. Here, we present a thermally degradable metal butyldithiocarbamate-based solution approach to fabricate Cu2ZnSn(S,Se)(4) solar cells. Low-cost Cu2O, ZnO, and SnO were used as the starting materials and were dissolved in the ethanol solution of butyldithiocarbamic acid. By tuning the composition of the Cu2ZnSn(S,Se)(4) thin film, a power conversion efficiency of 6.03% on the basis of the active area has been achieved.

引用

页码：10042 / 10047

页数：6

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