Preparation and the adsorption ability of thiolated magnetic core-shell Fe3O4@SiO2@C-SH for removing Hg2+ in water solution

被引:32
作者
Shi, Zhennan [1 ]
Xu, Chen [1 ]
Lu, Peng [1 ]
Fan, Lu [1 ]
Liu, Yana [1 ]
Wang, Yingxi [1 ]
Liu, Li [1 ]
Li, Ling [1 ]
机构
[1] Hubei Univ, Minist Educ, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Key Lab Synth & Applicat Organ Funct Mol, Wuhan 430062, Hubei, Peoples R China
关键词
Functional; Composite materials; Magnetic materials; AQUEOUS-SOLUTION; NANOPARTICLES; HG(II);
D O I
10.1016/j.matlet.2018.04.098
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A thiolated magnetic double- layered core- shell particles Fe3O4@SiO2@C-SH is synthesized and characterized. The application in Hg2+ removal is discussed. The removal can finished in 10 min with high efficiency, and the maximum adsorption capacity is 184.00 mg/ g. The adsorption fits the Freundlich adsorption isotherm and the adsorption kinetic is the second-order kinetic. Through DubininRadushkevich (D-R) isothermal adsorption analysis, it is found the adsorption for Hg2+ is mainly physical adsorption, accompanied by chemical one. The method provides a new way for designing double-layered materials aiming to remove heavy metal in waste water. (C) 2018 Elsevier B. V. All rights reserved.
引用
收藏
页码:130 / 133
页数:4
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