Initiation at Snail's Pace: Design and Applications of Latent Olefin Metathesis Catalysts Featuring Chelating Alkylidene Ligands

被引：68

作者：

Szadkowska, Anna ^{[1
]}

Grela, Karol ^{[1
]}

机构：

[1] Polish Acad Sci, Inst Organ Chem, PL-01224 Warsaw, Poland

来源：

CURRENT ORGANIC CHEMISTRY | 2008年 / 12卷 / 18期

关键词：

D O I：

10.2174/138527208786786264

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This review is devoted to recent advances in the design and application of so-called "dormant" or "latent" ruthenium olefin metathesis catalysts bearing chelating alkylidene ligands. Selected ruthenium complexes of controllable initiation behaviour are presented. Applications of these complexes in various metathesis reactions, including polymerization, are described.

引用

页码：1631 / 1647

页数：17

共 53 条

[21]

2-0

[22]

Grela K., 2007, DE Patent Application, Patent No. [DE102007020694.3, 1020070206943]

[23]

Grubbs R.H., 2003, HDB METATHESIS, V3

[24] Ruthenium quinoline and quinoxaline complexes: Thermally triggered initiators for ring opening metathesis polymerization [J].

Gstrein, Xaver ;

Burtscher, Daniel ;

Szadkowska, Anna ;

Barbasiewicz, Michal ;

Stelzer, Franz ;

Grela, Karol ;

Slugovc, Christian .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2007, 45 (15) :3494-3500

[25] A highly active aqueous olefin metathesis catalyst bearing a quaternary ammonium group [J].

Gulajski, Lukasz ;

Michrowska, Anna ;

Naroznik, Joanna ;

Kaczmarska, Zuzanna ;

Rupnicki, Leszek ;

Grela, Karol .

CHEMSUSCHEM, 2008, 1 (1-2) :103-109

[26] New tunable catalysts for olefin metathesis: Controlling the initiation through electronic factors [J].

Gulajski, Lukasz ;

Michrowska, Anna ;

Bujok, Robert ;

Grela, Karol .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006, 254 (1-2) :118-123

[27] Latent olefin metathesis catalysts featuring chelating alkylidenes [J].

Hejl, Andrew ;

Day, Michael W. ;

Grubbs, Robert H. .

ORGANOMETALLICS, 2006, 25 (26) :6149-6154

[28] Ru complexes bearing bidentate carbenes: from innocent curiosity to uniquely effective catalysts for olefin metathesis [J].

Hoveyda, AH ;

Gillingham, DG ;

Van Veldhuizen, JJ ;

Kataoka, O ;

Garber, SB ;

Kingsbury, JS ;

Harrity, JPA .

ORGANIC & BIOMOLECULAR CHEMISTRY, 2004, 2 (01) :8-23

[29] Ruthenium catalyst with a chelating pyridinyl-alcoholato ligand for application in linear alkene metathesis [J].

Jordaan, Margaritha ;

Vosloo, H. C. Manie .

ADVANCED SYNTHESIS & CATALYSIS, 2007, 349 (1-2) :184-192

[30]

KADYROW R, CHEM IND SE IN PRESS

← 1 2 3 4 5 6 →