Low temperature ceramic fuel cells using all nano composite materials

被引:48
作者
Fan, Liangdong [1 ,2 ]
Wang, Chengyang [2 ]
Zhu, Bin [1 ]
机构
[1] Royal Inst Technol KTH, Dept Energy Technol, S-10044 Stockholm, Sweden
[2] Tianjin Univ, Key Lab Green Chem Technol, Minist Educ, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China
基金
瑞典研究理事会;
关键词
Solid oxide fuel cells; Ceramic fuel cells; All nano composite; In-situ sintering; Thermal cycle stability; FE BIMETALLIC ANODE; CARBONATE COMPOSITE; ELECTROLYTE; CATHODES; SOFCS; FILM;
D O I
10.1016/j.nanoen.2012.04.004
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The shift to low operational temperature of solid oxide or ceramic fuel cells has induced many new concepts and novel technologies. In the present study, fuel cell assembled by all nano composite materials - NiO/Fe2O3-SDC anode, SDC-carbonate electrolyte and lithiated NiO/ZnO cathode - is investigated. A range of techniques, i.e., X-ray diffraction (XRD), Scanning electron microscopy (SEM) and electrochemical impedance spectroscopy as well as polarization measurements are employed to characterize the crystalline structures, morphologies and electrochemical properties of the synthesized nanocomposite materials and cells. Performance comparison is made between single cells with and without a pre-sintering process. Finally, single cell short term stability and thermo cycle behaviors are also examined. Combined the facile fabrication process, relative high performance and reasonable stability, the current all nanocomposite system may be a promising functional system for low temperature ceramic fuel cells. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:631 / 639
页数:9
相关论文
共 45 条
[1]   Catalytic activity of bimetallic nickel alloys for solid-oxide fuel cell anode reactions from density-functional theory [J].
An, Wei ;
Gatewood, Daniel ;
Dunlap, Brett ;
Turner, C. Heath .
JOURNAL OF POWER SOURCES, 2011, 196 (10) :4724-4728
[2]   High-performance solid-oxide fuel cell cathodes based on cobaltite nanotubes [J].
Bellino, Martin G. ;
Sacanell, Joaquin G. ;
Lamas, Diego G. ;
Leyva, Ana G. ;
Walsoe de Reca, Noemi E. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (11) :3066-+
[3]   Gadolinia-doped ceria mixed with alkali carbonates for solid oxide fuel cell applications: I. A thermal, structural and morphological insight [J].
Benamira, M. ;
Ringuede, A. ;
Albin, V. ;
Vannier, R. -N. ;
Hildebrandt, L. ;
Lagergren, C. ;
Cassir, M. .
JOURNAL OF POWER SOURCES, 2011, 196 (13) :5546-5554
[4]  
Benamira M., 2011, International Journal of Hydrogen Energy, P1
[5]   Impedance spectroscopy studies of Gd-CeO2-(LiNa)CO3 nano composite electrolytes for low temperature SOFC applications [J].
Chockalingam, Rajalekshmi ;
Basu, Suddhasatwa .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2011, 36 (22) :14977-14983
[6]   QUANTITATIVE INTERPRETATION OF X-RAY-DIFFRACTION PATTERNS OF MIXTURES .1. MATRIX-FLUSHING METHOD FOR QUANTITATIVE MULTICOMPONENT ANALYSIS [J].
CHUNG, FH .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1974, 7 (DEC1) :519-525
[7]   Samarium doped ceria-(Li/Na)2CO3 composite electrolyte and its electrochemical properties in low temperature solid oxide fuel cell [J].
Di, Jing ;
Chen, Mingming ;
Wang, Chengyang ;
Zheng, Jiaming ;
Fan, Liangdong ;
Zhu, Bin .
JOURNAL OF POWER SOURCES, 2010, 195 (15) :4695-4699
[8]   High performance anode-supported solid oxide fuel cell based on thin-film electrolyte and nanostructured cathode [J].
Ding, Changsheng ;
Hashida, Toshiyuki .
ENERGY & ENVIRONMENTAL SCIENCE, 2010, 3 (11) :1729-1731
[9]   Study of a Li-Ni oxide mixture as a novel cathode for molten carbonate fuel cells by electrochemical impedance spectroscopy [J].
Escudero, MJ ;
Nóvoa, XR ;
Rodrigo, T ;
Daza, L .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 2002, 32 (08) :929-936
[10]  
Fan L., 2011, INT J HYDROGEN ENERG