Removal of Cr(III) from aqueous solutions using P-EAn and P-MAn/PVDF composite membranes

被引:1
作者
Gurler, Berrin [1 ]
Ozkorucuklu, Sabriye Percin [2 ]
Kir, Esengul [2 ]
Ozdemir, Kamile [2 ]
机构
[1] Mehmet Akif Ersoy Univ, Golhisar Hlth Serv Vocat Sch, Dept Pharm, TR-15400 Golhisar Burdur, Turkey
[2] Suleyman Demirel Univ, Dept Chem, TR-32100 Isparta, Turkey
关键词
Composite membrane; Cr(III); Donnan dialysis; Poly-N-ethylaniline; Poly-N-methylaniline; ANION-EXCHANGE MEMBRANES; DONNAN DIALYSIS; HEXAVALENT CHROMIUM; WASTE-WATER; RED MUD; TRANSPORT; RECOVERY; IONS; POLYANILINE;
D O I
10.1080/19443994.2013.791786
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
In this work, composite membranes were prepared by chemical polymerization of a thin layer of substitute anilines (methylaniline and ethylaniline) in the presence of an oxidant on the surface polyvinylidenefluoride (PVDF) membrane support sheet. Poly-N-ethylaniline (P-EAn) and poly-N-methylaniline (P-MAn)/PVDF composite membranes were obtained from this polymerization. Scanning electron microscopy, Fourier transform infrared spectroscopy, and atomic force microscopy studies for composite membranes confirmed substitute anilines loading on the PVDF membrane. The membrane thickness and their ion-exchange capacities were also measured. Donnan dialysis experiments were performed using P-EAn and P-MAn/PVDF composite membranes for the removal of chromium (III) from aqueous solution. The flux values (J) of Cr(III) were obtained at 25 degrees C. The flux value of Cr(III) for P-EAn/PVDF composite membranes was higher than the other membrane because of the high ion-exchange capacity.
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页码:5721 / 5726
页数:6
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