Synthesis and characterization of Zn3Ta2O8 nanomaterials by hydrothermal method

被引：8

作者：

Birdeanu, M. ^{[1
]}

Birdeanu, A. -V. ^{[2
]}

Gruia, A. S. ^{[3
]}

Fagadar-Cosma, E. ^{[4
]}

Avram, C. N. ^{[3
]}

机构：

[1] Natl Inst Res & Dev Electrochem & Condensed Matte, Timisoara 300224, Romania

[2] Natl R&D Inst Welding & Mat Testing ISIM Timisoa, Timisoara 300222, Romania

[3] West Univ Timisoara, Fac Phys, Timisoara 300223, Romania

[4] Romanian Acad, Inst Chem Timisoara, Timisoara 300223, Romania

来源：

JOURNAL OF ALLOYS AND COMPOUNDS | 2013年 / 573卷

关键词：

Nanostructures; Zn3Ta2O8; Optical properties; Hydrothermal synthesis; Ab initio calculations; LUMINESCENCE PROPERTIES; THIN; TA2ZN3O8; OXIDE;

D O I：

10.1016/j.jallcom.2013.03.274

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Zn3Ta2O8 has been synthesized by hydrothermal method using tantalum (V) oxide and zinc nitrate. The crystal structure and microstructure, phase composition and the absorption of Zn3Ta2O8 nanomaterials were characterized by X-ray diffraction, FT/IR measurements, UV-VIS measurements, PL measurements, SEM and AFM techniques and BET analysis. XRD results show the single phase of Zn3Ta2O8 and the average particle size that is 52 nm. This narrow nanometer size was also confirmed by AFM measurements. BET analysis revealed that the nanomaterials are mesoporous. The PL spectra show the blue luminescence of Ta2Zn3O8. Besides, in the present work we report ab initio calculations regarding electronic properties of Zn3Ta2O8; the theoretical results are compared with the experimental ones. (C) 2013 Elsevier B. V. All rights reserved.

引用

页码：53 / 57

页数：5

共 22 条

[21] Applicability of the BET method for determining surface areas of microporous metal-organic frameworks
Walton, Krista S.
Snurr, Randall Q.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (27) : 8552 - 8556
[22] Synthesis and luminescence properties of Eu3+-doped ZnO nanocrystals by a hydrothermal process
Zhong, Mingya
Shan, Guiye
Li, Yajun
Wang, Guorui
Liu, Yichun
[J]. MATERIALS CHEMISTRY AND PHYSICS, 2007, 106 (2-3) : 305 - 309

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