Preparation and photo-catalytic performance of β2-SiW11/PANI/TiO2 photo-catalyst

被引:3
作者
Yang, Mingrui [1 ]
Ma, Ronghua [1 ]
Chen, Lin [1 ]
Zhang, Chengli [1 ]
Cao, Rui [1 ]
Wen, Qi [1 ]
机构
[1] Qiqihar Univ, Coll Chem & Chem Engn, Qiqihar 161006, Peoples R China
关键词
Heteropoly tungstate; TiO2; photo-catalytic performance; methylene blue; PHOTOCATALYTIC ACTIVITY; DEGRADATION; TIO2; COMPOSITES; REMOVAL; ACID;
D O I
10.1080/00958972.2020.1849641
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Using heteropoly tungstate beta(2)-K8SiW11O39 center dot xH(2)O as the active component, the tungstate was loaded on PANI/TiO2 by the dipping method to prepare a composite photo-catalyst beta(2)-SiW11/PANI/TiO2. The new ternary composite material, beta(2)-SiW11/PANI/TiO2, was characterized by IR, UV, TG, XPS, XRD and SEM. Meanwhile, the degradation of methylene blue solution was used as a probe reaction to evaluate the photo-catalytic performance of beta(2)-SiW11/PANI/TiO2. The effect of solution pH and amount of composite material on photo-catalytic activity was investigated. Compared with TiO2 and silicate, the composite material beta(2)-SiW11/PANI/TiO2 as photo-catalyst exhibited enhanced photo-catalytic performance due to the synergic effect between TiO2 and heteropoly tungstate. Under optimum conditions, 92.58% of the dye was decomposed in 150 min. Our present findings will have a profound effect on the use of beta(2)-SiW11/PANI/TiO2 composite as photo-catalytic material.
引用
收藏
页码:3420 / 3430
页数:11
相关论文
共 39 条
[11]  
Grabsi Mohammed, 2019, Environmental Nanotechnology, Monitoring and Management, V12, DOI 10.1016/j.enmm.2019.100269
[12]   Surface acidity, catalytic and photocatalytic activities of new type H3PW12O40/Sn-TiO2 nanoparticles [J].
Hassan, Shawky M. ;
Ahmed, Awad, I ;
Mannaa, Mohammed A. .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2019, 577 :147-157
[13]   Preparation and photocatalytic performance of tungstovanadophosphoric heteropoly acid salts [J].
Ji, Dandan ;
Xue, Rong ;
Zhou, Maojuan ;
Zhu, Ying ;
Zhang, Fengshan ;
Zang, Lihua .
RSC ADVANCES, 2019, 9 (32) :18320-18325
[14]   Efficiency of various recent wastewater dye removal methods: A review [J].
Katheresan, Vanitha ;
Kansedo, Jibrail ;
Lau, Sie Yon .
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING, 2018, 6 (04) :4676-4697
[15]   Photocatalytic activity of polyaniline/Fe-doped TiO2 composites by in situ polymerization method [J].
Koysuren, Ozcan ;
Koysuren, H. Nagehan .
JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY, 2019, 56 (03) :267-276
[16]   Photocatalytic performance of mesoporous composites of TiO2-ZrO2 and phosphotungstic acid [J].
Li, Qinlong ;
Feng, Caiting ;
Wu, Panfeng ;
Yuan, Xiaoxiao ;
Hu, Huaiming ;
Xue, Ganglin .
JOURNAL OF MATERIALS SCIENCE, 2020, 55 (08) :3195-3211
[17]  
Liu W.J., 2018, NANOTECHNOL ENV ENG, V3
[18]   Preparation and photocatalytic kinetic study of ternary composite photocatalyst 12-phosphotungstic acid/PANI/SnO2 [J].
Ma Rong-Hua ;
Sun Yan .
JOURNAL OF COORDINATION CHEMISTRY, 2019, 72 (16) :2749-2762
[19]  
Moosavifar M., 2017, MOD CHEM APPL, V5, P1
[20]   Photocatalytic Performance of H6P2W18O62/TiO2 Nanocomposite Encapsulated into Beta Zeolite under UV Irradiation in the Degradation of Methyl Orange [J].
Moosavifar, Maryam ;
Bagheri, Samira .
PHOTOCHEMISTRY AND PHOTOBIOLOGY, 2019, 95 (02) :532-542