Palladium-catalyzed desymmetric hydrophosphination of 3,3-disubstituted cyclopropenes

被引：0
|
作者：
Yuen, On Ying [1 ,2 ]
So, Chau Ming [1 ,2 ,3 ]
机构：
[1] Hong Kong Polytech Univ, State Key Lab Chem Biol & Drug Discovery, Hung Hom, Kowloon, Hong Kong, Peoples R China
[2] Hong Kong Polytech Univ, Dept Appl Biol & Chem Technol, Hung Hom, Kowloon, Hong Kong, Peoples R China
[3] Hong Kong Polytech Univ, Shenzhen Res Inst, Shenzhen 518000, Peoples R China
来源：
CHEM CATALYSIS | 2022年 / 2卷 / 11期
基金：
中国国家自然科学基金;
关键词：
D O I：
10.1016/j.checat.2022.10.021
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In this issue of Chem Catalysis, Wang and co-workers report palladium-catalyzed diastereo- and enantioselective desymmetric hydrophosphination of 3,3-disubstituted cyclopropenes. This pathway allows the synthesis of chiral phosphine compounds with two vicinal carbon stereocenters with excellent diastereo- and enantioselectivity. Further, hydrophosphination products can be transformed synthetically for multiple applications.
引用
收藏
页码：2805 / 2807
页数：3
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