High performance visible light driven photocatalysts silver halides and graphitic carbon nitride (X = Cl, Br, I) nanocomposites

被引:55
作者
Lan, Yonghuan [1 ]
Qian, Xiuzhen [1 ]
Zhao, Chongjun [1 ,2 ]
Zhang, Zhuomin [1 ]
Chen, Xin [1 ]
Li, Zhen [2 ]
机构
[1] E China Univ Sci & Technol, Sch Mat Sci & Engn, Shanghai Key Lab Adv Polymer Mat, Key Lab Ultrafine Mat,Minist Educ, Shanghai 200237, Peoples R China
[2] Univ Wollongong, Inst Superconducting & Elect Mat, Wollongong, NSW 2500, Australia
基金
中国国家自然科学基金; 澳大利亚研究理事会;
关键词
g-C3N4; Silver halides; Visible light; Photocatalysis; AG-AT-AGCL; STABLE PHOTOCATALYST; ELECTRONIC-STRUCTURE; HEATING MELAMINE; METHYL-ORANGE; EFFICIENT; DEGRADATION; COMPOSITES; OXIDATION; POLYMER;
D O I
10.1016/j.jcis.2012.12.033
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Novel visible light-driven phtotocatalysts composed by silver halides and graphitic carbon nitride (i.e. AgX@g-C3N4, X = Cl, Br, I) were synthesized by in situ precipitation of AgX nanoparticles on the surface of sheet-like g-C3N4. The resultant AgX@g-C3N4 nanocomposites were characterized with state-of-the-art instruments, showing significant enhancement in photocatalytic degradation of methyl orange under the irradiation of visible light. Their excellent photocatalytic performance is attributed to the efficient separation of photogenerated electron-hole pairs and their higher photostability in comparison with pure AgX. (C) 2012 Elsevier Inc. All rights reserved.
引用
收藏
页码:75 / 80
页数:6
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