Synthesis and aqueous solution properties of novel hydrophilic-hydrophilic block copolymers based on tertiary amine methacrylates

被引:122
|
作者
Butun, V [1 ]
Billingham, NC [1 ]
Armes, SP [1 ]
机构
[1] UNIV SUSSEX,SCH CHEM PHYS & ENVIRONM SCI,BRIGHTON BN1 9QJ,E SUSSEX,ENGLAND
关键词
D O I
10.1039/a700772h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A series of near-monodisperse novel diblock copolymers based on tertiary amine methacrylates has been synthesised using group transfer polymerisation chemistry; subtle differences in basicity between the two blocks lead to interesting aqueous solution behaviour, including pH-induced micellisation and very high surface activity.
引用
收藏
页码:671 / 672
页数:2
相关论文
共 50 条
  • [1] Synthesis and aqueous solution properties of novel hydrophilic/hydrophilic block copolymers based on tertiary amine methacrylates and poly(ethylene oxide).
    Bailey, L
    Vamvakaki, M
    Billingham, NC
    Armes, SP
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1999, 218 : U443 - U444
  • [2] Novel hydrophilic-hydrophilic block copolymers based on poly(vinyl alcohol)
    Forder, C
    Patrickios, CS
    Billingham, NC
    Armes, SP
    CHEMICAL COMMUNICATIONS, 1996, (07) : 883 - 884
  • [3] Facile synthesis of hydrophilic-hydrophilic copolymers via atom-transfer radical polymerization.
    Furlong, SA
    Armes, SP
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2000, 219 : U437 - U437
  • [4] Double-hydrophilic linear and star copolymers bearing diol and tertiary amine groups: Synthesis and aqueous solution characterization.
    Hadjiyannakou, SC
    Georgiou, T
    Vamvakaki, M
    Patrickios, CS
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2001, 221 : U338 - U338
  • [5] Solution Behavior of Double-Hydrophilic Block Copolymers in Dilute Aqueous Solution
    Casse, Olivier
    Shkilnyy, Andriy
    Linders, Juergen
    Mayer, Christian
    Haeussinger, Daniel
    Voelkel, Antje
    Thuenemann, Andreas F.
    Dimova, Rumiana
    Coelfen, Helmut
    Meier, Wolfgang
    Schlaad, Helmut
    Taubert, Andreas
    MACROMOLECULES, 2012, 45 (11) : 4772 - 4777
  • [6] Synthesis and solution properties of water-soluble hydrophilic-hydrophobic block copolymers
    Baines, FL
    Billingham, NC
    Armes, SP
    MACROMOLECULES, 1996, 29 (10) : 3416 - 3420
  • [7] Self-assembly of double-hydrophilic block copolymers in aqueous solution
    Blanazs, Adam
    Warren, Nicholas J.
    Armes, Steven P.
    Ryan, Anthony J.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2011, 242
  • [8] Synthesis and aqueous solution properties of novel zwitterionic block copolymers
    Lowe, AB
    Billingham, NC
    Armes, SP
    CHEMICAL COMMUNICATIONS, 1997, (11) : 1035 - 1036
  • [9] Self-assembly of double hydrophilic block copolymers in concentrated aqueous solution
    Blanazs, Adam
    Warren, Nicholas J.
    Lewis, Andrew L.
    Armes, Steven P.
    Ryan, Anthony J.
    SOFT MATTER, 2011, 7 (14) : 6399 - 6403
  • [10] SYNTHESIS AND SOLUTION PROPERTIES OF HYDROPHILIC SILICONE-GRAFTED COPOLYMERS
    MAEDA, K
    YUKI, Y
    KOBUNSHI RONBUNSHU, 1992, 49 (05) : 433 - 439