Synthesis and aqueous solution properties of novel hydrophilic-hydrophilic block copolymers based on tertiary amine methacrylates

被引：122
作者：
Butun, V [1 ]
Billingham, NC [1 ]
Armes, SP [1 ]
机构：
[1] UNIV SUSSEX,SCH CHEM PHYS & ENVIRONM SCI,BRIGHTON BN1 9QJ,E SUSSEX,ENGLAND
来源：
CHEMICAL COMMUNICATIONS | 1997年 / 07期
关键词：
D O I：
10.1039/a700772h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A series of near-monodisperse novel diblock copolymers based on tertiary amine methacrylates has been synthesised using group transfer polymerisation chemistry; subtle differences in basicity between the two blocks lead to interesting aqueous solution behaviour, including pH-induced micellisation and very high surface activity.
引用
收藏
页码：671 / 672
页数：2
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  • [1] Synthesis and solution properties of water-soluble hydrophilic-hydrophobic block copolymers
    Baines, FL
    Billingham, NC
    Armes, SP
    [J]. MACROMOLECULES, 1996, 29 (10) : 3416 - 3420
  • [2] Micellization of poly(2-(dimethylamino)ethyl methacrylate-block-methyl methacrylate) copolymers in aqueous solution
    Baines, FL
    Armes, SP
    Billingham, NC
    Tuzar, Z
    [J]. MACROMOLECULES, 1996, 29 (25) : 8151 - 8159
  • [3] OXYANIONS CATALYZE GROUP-TRANSFER POLYMERIZATION TO GIVE LIVING POLYMERS
    DICKER, IB
    COHEN, GM
    FARNHAM, WB
    HERTLER, WR
    LAGANIS, ED
    SOGAH, DY
    [J]. MACROMOLECULES, 1990, 23 (18) : 4034 - 4041
  • [4] Synthesis and aqueous solution characterization of dihydrophilic block copolymers of methyl vinyl ether and methyl triethylene glycol vinyl ether
    Forder, C
    Patrickios, CS
    Armes, SP
    Billingham, NC
    [J]. MACROMOLECULES, 1996, 29 (25) : 8160 - 8169
  • [5] Novel hydrophilic-hydrophilic block copolymers based on poly(vinyl alcohol)
    Forder, C
    Patrickios, CS
    Billingham, NC
    Armes, SP
    [J]. CHEMICAL COMMUNICATIONS, 1996, (07) : 883 - 884
  • [6] POLY(ALKYL METHACRYLATE-B-SULFONATED GLYCIDYL METHACRYLATE) - A NEW AMPHIPHILIC POLYMERIC SURFACTANT FOR THE PREPARATION AND STABILIZATION OF POLYMER ACRYLIC LATTICES IN AQUEOUS-MEDIUM
    LEEMANS, L
    FAYT, R
    TEYSSIE, P
    DEJAEGER, NC
    [J]. MACROMOLECULES, 1991, 24 (22) : 5922 - 5925
  • [7] SYNTHESIS OF NEW AMPHIPHILIC BLOCK COPOLYMERS - BLOCK COPOLYMER OF SULFONATED GLYCIDYL METHACRYLATE AND ALKYL METHACRYLATE
    LEEMANS, L
    FAYT, R
    TEYSSIE, P
    [J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1990, 28 (05) : 1255 - 1262
  • [8] Synthesis of polybetaines with narrow molecular mass distribution and controlled architecture
    Lowe, AB
    Billingham, NC
    Armes, SP
    [J]. CHEMICAL COMMUNICATIONS, 1996, (13) : 1555 - 1556
  • [9] pH-dependent micellization of poly(2-vinylpyridine)-block-poly(ethylene oxide)
    Martin, TJ
    Prochazka, K
    Munk, P
    Webber, SE
    [J]. MACROMOLECULES, 1996, 29 (18) : 6071 - 6073
  • [10] GROUP-TRANSFER POLYMERIZATION .1. A NEW CONCEPT FOR ADDITION POLYMERIZATION WITH ORGANO-SILICON INITIATORS
    WEBSTER, OW
    HERTLER, WR
    SOGAH, DY
    FARNHAM, WB
    RAJANBABU, TV
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (17) : 5706 - 5708
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