A MOF-membrane based on the covalent bonding driven assembly of a NMOF with an organic oligomer and its application in membrane reactors

被引：47

作者：

Jiang, Wei-Ling ^{[1
]}

Ding, Luo-Gang ^{[1
]}

Yao, Bing-Jian ^{[1
]}

Wang, Jian-Cheng ^{[1
]}

Chen, Gong-Jun ^{[1
]}

Li, Yan-An ^{[1
]}

Ma, Jian-Ping ^{[1
]}

Ji, Jun ^{[1
]}

Dong, Ying ^{[1
]}

Dong, Yu-Bin ^{[1
]}

机构：

[1] Shandong Normal Univ, Coll Chem Chem Engn & Mat Sci, Collaborat Innovat Ctr Funct Probes Chem Imaging, Key Lab Mol & Nano Probes,Minist Educ, Jinan 250014, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 93期

关键词：

CATALYTIC-PROPERTIES; FRAMEWORK; NANOPARTICLES; POLYMERIZATION; SEPARATION;

D O I：

10.1039/c6cc06427b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A UiO-66-MOF-based membrane UiO-66-TEM (1) was prepared by the assembly of methacrylamide-decorated UiO-66-NH-Met with a thiol side chain-attached polysiloxane (PSI-SH) via a photoinduced thiol-ene click reaction. The obtained membrane 1 can be a platform to support Au nanoparticles (Au NPs) to generate an Au-MOF-polymer composite membrane Au@UiO-66-TEM (2). 1 and 2 can be used to build highly efficient continuous flow-through membrane reactors for Knoevenagel condensation of 4-nitrobenzaldehyde with malononitrile and 4-nitrophenol (4-NP) reduction at ambient temperature, respectively.

引用

收藏

页码：13564 / 13567

页数：4

相关论文

共 18 条

[1] In Situ Modification of Metal-Organic Frameworks in Mixed-Matrix Membranes [J].

Denny, Michael S., Jr. ;

Cohen, Seth M. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (31) :9029-9032

[2] Fabrication of COF-MOF Composite Membranes and Their Highly Selective Separation of H2/CO2 [J].

Fu, Jingru ;

Das, Saikat ;

Xing, Guolong ;

Ben, Teng ;

Valtchev, Valentin ;

Qiu, Shilun .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (24) :7673-7680

[3] Catalytic activity of supported au nanoparticles deposited from block copolymer micelles [J].

Jaramillo, TF ;

Baeck, SH ;

Roldan Cuenya, B ;

McFarland, EW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (24) :7148-7149

[4] Microwave-Assisted Cyanation of an Aryl Bromide Directly on a Metal-Organic Framework [J].

Kim, Min ;

Garibay, Sergio J. ;

Cohen, Seth M. .

INORGANIC CHEMISTRY, 2011, 50 (03) :729-731

[5] Pd(0)@UiO-68-AP: chelation-directed bifunctional heterogeneous catalyst for stepwise organic transformations [J].

Li, Yan-An ;

Yang, Song ;

Liu, Qi-Kui ;

Chen, Gong-Jun ;

Ma, Jian-Ping ;

Dong, Yu-Bin .

CHEMICAL COMMUNICATIONS, 2016, 52 (39) :6517-6520

[6] Crystal-Plane Effects on the Catalytic Properties of Au/TiO2 [J].

Liu, Lichen ;

Gu, Xianrui ;

Cao, Yuan ;

Yao, Xiaojiang ;

Zhang, Lei ;

Tang, Changjin ;

Gao, Fei ;

Dong, Lin .

ACS CATALYSIS, 2013, 3 (12) :2768-2775

[7] Thiol-ene "click" reactions and recent applications in polymer and materials synthesis: a first update [J].

Lowe, Andrew B. .

POLYMER CHEMISTRY, 2014, 5 (17) :4820-4870

[8] Nucleic Acid-Metal Organic Framework (MOF) Nanoparticle Conjugates [J].

Morris, William ;

Briley, William E. ;

Auyeung, Evelyn ;

Cabezas, Maria D. ;

Mirkin, Chad A. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (20) :7261-7264

[9] Postsynthetic Modification of a Metal-Organic Framework for Stabilization of a Hemiaminal and Ammonia Uptake [J].

Morris, William ;

Doonan, Christian J. ;

Yaghi, Omar M. .

INORGANIC CHEMISTRY, 2011, 50 (15) :6853-6855

[10] Visualizing MOF Mixed Matrix Membranes at the Nanoscale: Towards Structure-Performance Relationships in CO2/CH4 Separation Over NH2-MIL-53(Al)@PI [J].

Rodenas, Tania ;

van Dalen, Marion ;

Garcia-Perez, Elena ;

Serra-Crespo, Pablo ;

Zornoza, Beatriz ;

Kapteijn, Freek ;

Gascon, Jorge .

ADVANCED FUNCTIONAL MATERIALS, 2014, 24 (02) :249-256