Mo- and Fe-Modified Ni(OH)2/NiOOH Nanosheets as Highly Active and Stable Electrocatalysts for Oxygen Evolution Reaction

被引:314
作者
Jin, Yanshuo [1 ]
Huang, Shangli [2 ]
Yue, Xin [1 ]
Du, Hongyu [3 ]
Shen, Pei Kang [1 ,2 ]
机构
[1] Sun Yat Sen Univ, Sch Mat Sci & Engn, Guangzhou 510275, Guangdong, Peoples R China
[2] Guangxi Univ, Collaborat Innovat Ctr Sustainable Energy Mat, Nanning 530004, Peoples R China
[3] Sun Yat Sen Univ, Sch Phys, Guangzhou 510275, Guangdong, Peoples R China
来源
ACS CATALYSIS | 2018年 / 8卷 / 03期
关键词
Mo and Fe dual-modified; nickel (oxy)hydroxide; nanosheets; water splitting; oxygen evolution; LAYERED DOUBLE HYDROXIDE; WATER OXIDATION; METAL ELECTROCATALYST; HIGH-PERFORMANCE; EFFICIENT; OXIDE; NANOTUBES; CATALYSTS; STATES;
D O I
10.1021/acscatal.7b04226
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Highly active and stable electrocatalysts for oxygen evolution reaction (OER) are required for industrial hydrogen production. Herein, we report Mo and Fe modification as a synergistic effect to enhance both activity and stability for OER The Mo- and Fe-modified Ni(OH)(2)/NiOOH nanosheets needs an overpotential of only similar to 280 mV to achieve a current density of 100 mA cm(-2) and shows no evidence of degradation after 50 h at such high current density, outperforming all OER catalysts reported to date. This work may provide options for the design and preparation of promising OER electrocatalysts.
引用
收藏
页码:2359 / 2363
页数:9
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