The chemistry of amine radical cations produced by visible light photoredox catalysis

被引：371
作者：
Hu, Jie [1 ]
Wang, Jiang [1 ]
Nguyen, Theresa H. [1 ]
Zheng, Nan [1 ]
机构：
[1] Univ Arkansas, Dept Chem, Fayetteville, AR 72701 USA
来源：
BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2013年 / 9卷
关键词：
alpha-amino radical; amine radical cation; catalysis; distonic ion; free radical; iminium ion; photoredox; visible light; C-BOND-CLEAVAGE; PHOTOINDUCED ELECTRON-TRANSFER; TRANSITION-METAL-COMPLEXES; ALPHA-AMINOALKYL RADICALS; PROTON-TRANSFER REACTIONS; DUAL CATALYSIS; H BONDS; COORDINATION-COMPOUNDS; SYNTHETIC APPLICATIONS; COUPLING REACTIONS;
D O I：
10.3762/bjoc.9.234
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Amine radical cations are highly useful reactive intermediates in amine synthesis. They have displayed several modes of reactivity leading to some highly sought-after synthetic intermediates including iminium ions, a-amino radicals, and distonic ions. One appealing method to access amine radical cations is through one-electron oxidation of the corresponding amines under visible light photoredox conditions. This approach and subsequent chemistries are emerging as a powerful tool in amine synthesis. This article reviews synthetic applications of amine radical cations produced by visible light photocatalysis.
引用
收藏
页码：1977 / 2001
页数：25
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