An effective protocol for the synthesis enantiomerically pure 4-substituted oxetane-2-ones

被引：8
|
作者：
Balakier, Tomasz [1 ]
Chaladaj, Wojciech [1 ]
Jurczak, Janusz [1 ]
Adamus, Grazyna [2 ]
Kowalczuk, Marek [2 ]
机构：
[1] Polish Acad Sci, Inst Organ Chem, PL-01224 Warsaw, Poland
[2] Polish Acad Sci, Ctr Polymer & Carbon Mat, PL-41819 Zabrze, Poland
来源：
TETRAHEDRON | 2013年 / 69卷 / 24期
关键词：
Epoxide kinetic resolution; Carbonylation; beta-Lactones; Gram-scale synthesis; EPOXIDE CARBONYLATION; BETA-LACTONES; CATALYST; POLYMERIZATION; COMPLEXES;
D O I：
10.1016/j.tet.2013.04.020
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Six enantiomerically pure 4-substituted oxetane-2-ones (beta-lactones) were obtained using the known Jacobsen's catalytic hydrolytic resolution of racemic epoxides, followed by atmospheric pressure carbonylation reaction. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码：4990 / 4993
页数：4
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