An effective protocol for the synthesis enantiomerically pure 4-substituted oxetane-2-ones

被引：8

作者：

Balakier, Tomasz ^{[1
]}

Chaladaj, Wojciech ^{[1
]}

Jurczak, Janusz ^{[1
]}

Adamus, Grazyna ^{[2
]}

Kowalczuk, Marek ^{[2
]}

机构：

[1] Polish Acad Sci, Inst Organ Chem, PL-01224 Warsaw, Poland

[2] Polish Acad Sci, Ctr Polymer & Carbon Mat, PL-41819 Zabrze, Poland

来源：

TETRAHEDRON | 2013年 / 69卷 / 24期

关键词：

Epoxide kinetic resolution; Carbonylation; beta-Lactones; Gram-scale synthesis; EPOXIDE CARBONYLATION; BETA-LACTONES; CATALYST; POLYMERIZATION; COMPLEXES;

D O I：

10.1016/j.tet.2013.04.020

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Six enantiomerically pure 4-substituted oxetane-2-ones (beta-lactones) were obtained using the known Jacobsen's catalytic hydrolytic resolution of racemic epoxides, followed by atmospheric pressure carbonylation reaction. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：4990 / 4993

页数：4

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