Synthesis of New Metal-Free 1,4,8,11-Tetraaza[14]annulene Derivatives Using 2-Heteroaryl-substituted Trimethinium Salts

被引：11

作者：

Mehranpour, A. M. ^{[1
]}

Hashemnia, S. ^{[1
]}

Rad, J. Ameri ^{[1
]}

机构：

[1] Persian Gulf Univ, Bushehr 75169, Iran

来源：

JOURNAL OF HETEROCYCLIC CHEMISTRY | 2013年 / 50卷 / 04期

关键词：

ALKALINE-SOLUTIONS; REDOX CATALYSIS; COMPLEXES; DNA/RNA; NICKEL;

D O I：

10.1002/jhet.1104

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of 2-heteroaryl-substituted trimethinium salts (A, B, and C) with aromatic 1,2-diamines (a, b, c, d, and e) in acetonitrile/acetic acid leads to 6,13-disubstituted 1,4,8,11-tetraaza[14]annulene derivatives (1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14). The UV-vis spectral behavior of these compounds was examined in acetonitrile. Elemental analysis, IR, 1H-NMR, 13C-NMR, and mass spectra confirm the molecular structure of the newly synthesized compounds.

引用

页码：821 / 827

页数：7

共 18 条

[1]

ADAMS F, 1989, ANGEW CHEM, V101, P1043

[2]

Adams F., 1989, ANGEW CHEM, V101, P1046

[3] Cyclic voltammetry and spectroelectrochemical study of nickel and cobalt diphenyltetraazaannulene complexes [J].