Investigation of dielectric and piezoelectric properties in Pb(Ni1/3Nb2/3)O3-PbHfO3-PbTiO3 ternary system

被引：69

作者：

Tang, H. ^{[1
,2
,3
]}

Zhang, M. F. ^{[1
,4
]}

Zhang, S. J. ^{[1
,2
,3
]}

Feng, Y. J. ^{[2
,3
]}

Li, F. ^{[2
,3
]}

Shrout, T. R. ^{[1
]}

机构：

[1] Penn State Univ, Mat Res Inst, University Pk, PA 16802 USA

[2] Xi An Jiao Tong Univ, Minist Educ, Key Lab, Elect Mat Res Lab, Xian 710049, Peoples R China

[3] Xi An Jiao Tong Univ, Int Ctr Dielect Res, Xian 710049, Peoples R China

[4] Harbin Inst Technol, Ctr Composite Mat, Harbin 150080, Peoples R China

来源：

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY | 2013年 / 33卷 / 13-14期

关键词：

Pb(Ni1/3Nb2/3)O-3-PbHfO3-PbTiO3; Piezoelectric properties; Morphotropic phase boundary; Curie temperature; Rayleigh analysis; MORPHOTROPIC PHASE-BOUNDARY; FERROELECTRIC CERAMICS; TITANATE; OXIDE;

D O I：

10.1016/j.jeurceramsoc.2013.04.010

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The dielectric and piezoelectric properties were investigated in the (1 - x)Pb(Hf1-yTiy)O-3-xPb(Ni1/3Nb2/3)O-3 (PNN-PHT, x=0.05-0.50, y=0.55-0.70) ternary system. The morphotropic phase boundary (MPB) was determined by X-ray powder diffraction analysis. Isothermal map of Curie temperature (T-C) related to the compositions in the phase diagram was obtained. The optimum dielectric and piezoelectric properties were achieved in ceramics with the MPB compositions, with the maxima values being on the order of 6000 and 970pC/N, respectively. Rayleigh analysis was used to study the extrinsic contribution (domain wall motion) in PNN-PHT system, where the extrinsic contribution was found to be similar to 30% for composition 0.49PNN-0.51PHT(30/70), showing a high nonlinearity. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：2491 / 2497

页数：7

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