Comparison of microbiologically and enzymatically mediated Baeyer-Villiger oxidations: Synthesis of optically active caprolactones

被引：37
作者：
Alphand, V
Furstoss, R
PedragosaMoreau, S
Roberts, SM
Willetts, AJ
机构：
[1] FAC SCI LUMINY,GRP CHIM ORGAN & BIOORGAN,URA CNRS 1320,F-13288 MARSEILLE 9,FRANCE
[2] UNIV EXETER,DEPT CHEM,EXETER EX4 4QD,DEVON,ENGLAND
[3] UNIV EXETER,DEPT BIOL SCI,EXETER EX4 4QD,DEVON,ENGLAND
来源：
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1996年 / 15期
关键词：
D O I：
10.1039/p19960001867
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Optically active a-substituted caprolactones (7-substituted oxepan-2-ones) were obtained by biocatalysed Baeyer-Villiger oxidations of various a-substituted cyclohexanones using either whole-cells of Acinetobacter TD63 or a purified cyclohexanone monooxygenase from Ps. putida NCIMB 10007(MO2). A refinement of the previously established active site model is proposed.
引用
收藏
页码：1867 / 1872
页数：6
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