Recombinant oxalate decarboxylase: enhancement of a hybrid catalytic cascade for the complete electro-oxidation of glycerol

被引：20

作者：

Abdellaoui, Sofiene

Hickey, David P.

Stephens, Andrew R.

Minteer, Shelley D. ^{[1
]}

机构：

[1] Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 76期

基金：

美国国家科学基金会;

关键词：

BACILLUS-SUBTILIS; ELECTROCATALYTIC OXIDATION; ALCOHOLS; ELECTRODE; OXIDASE; GOLD; ACID;

D O I：

10.1039/c5cc06131h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complete electro-oxidation of glycerol to CO2 is performed through an oxidation cascade using a hybrid catalytic system combining a recombinant enzyme, oxalate decarboxylase from Bacillus subtilis, and an organic oxidation catalyst, 4-amino-TEMPO. This system is capable of electrochemically oxidizing glycerol at a carbon electrode collecting all 14 electrons per molecule.

引用

收藏

页码：14330 / 14333

页数：4

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