Analysis of electrocatalytic reaction schemes: distinction between rate-determining and potential-determining steps

被引：213

作者：

Koper, Marc T. M. ^{[1
,2
]}

机构：

[1] Leiden Univ, Leiden Inst Chem, NL-2300 RA Leiden, Netherlands

[2] Hokkaido Univ, Catalysis Res Ctr, Sapporo, Hokkaido 0010021, Japan

来源：

JOURNAL OF SOLID STATE ELECTROCHEMISTRY | 2013年 / 17卷 / 02期

关键词：

ELECTROLYTIC HYDROGEN EVOLUTION; COMPARING DEDONDER RELATIONS; OXYGEN REDUCTION; EXCHANGE CURRENT; ACID-SOLUTIONS; ADSORPTION; CATALYSIS; MECHANISM; METALS; TRENDS;

D O I：

10.1007/s10008-012-1918-x

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

This paper discusses the concepts of rate-determining step and potential-determining step in the context of electrocatalytic reaction schemes, illustrates how the simpler concept of potential-determining step often captures the essence of a bottleneck in a reaction scheme, and thereby provides straightforward hints for developing better catalysts.

引用

页码：339 / 344

页数：6

共 27 条

[1] Free energy relationships in electrochemistry: a history that started in 1935
Appleby, Anthony John
Heraclito Zagal, Jose
[J]. JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2011, 15 (7-8) : 1811 - 1832
[2] SOME APPLICATIONS OF THE GENERALIZED DEDONDER EQUATION TO INDUSTRIAL REACTIONS
BOUDART, M
[J]. INDUSTRIAL & ENGINEERING CHEMISTRY FUNDAMENTALS, 1986, 25 (01): : 70 - 75
[3] Finding the rate-determining step in a mechanism - Comparing DeDonder relations with the "degree of rate control"
Campbell, CT
[J]. JOURNAL OF CATALYSIS, 2001, 204 (02) : 520 - 524
[4] De Donder T, 1927, AFFINITE
[5] Dumesic J.A., 2008, Handbook of Heterogeneous Catalysis, P1445
[6] Analyses of reaction schemes using De Donder relations
Dumesic, JA
[J]. JOURNAL OF CATALYSIS, 1999, 185 (02) : 496 - 505
[7] Reply to finding the rate-determining step in a mechanism: Comparing DeDonder relations with the "degree of rate control"
Dumesic, JA
[J]. JOURNAL OF CATALYSIS, 2001, 204 (02) : 525 - 529
[8] Gerischer H., 1958, B SOC CHIM BELG, V67, P506, DOI [10.1002/bscb.19580670714, DOI 10.1002/BSCB.19580670714]
[9] Gottesfeld S., 2009, FUEL CELL CATALYSIS, P1
[10] Greeley J, 2009, NAT CHEM, V1, P552, DOI [10.1038/nchem.367, 10.1038/NCHEM.367]

← 1 2 3 →