ELECTRICAL CONDUCTIVITY AND DIELECTRIC RELAXATION STUDY OF POLYVINYL ACETATE/POLY METHYL METHACRYLATE BLENDS

被引：20
作者：
Ahmed, R. M. [1 ]
机构：
[1] Zagazig Univ, Fac Sci, Dept Phys, Zagazig 44519, Egypt
来源：
INTERNATIONAL JOURNAL OF MODERN PHYSICS B | 2012年 / 26卷 / 29期
关键词：
Conductivity; glass transition temperature; polymer blends; polymer films; AC CONDUCTIVITY; A.C; CONDUCTIVITY; MIXTURES;
D O I：
10.1142/S0217979212501597
中图分类号：
O59 [应用物理学];
学科分类号：
摘要：
Transparent films of PMMA (poly methyl methacrylate), PVAc (polyvinyl acetate) and their blends, have been prepared by using a solution-casting technique. The dielectric properties and the electrical conductivity are reported. The frequency and temperature dependence of the dielectric constant, epsilon' and tan delta, have been investigated for the studied samples in the frequency range from 1 kHz to 5 MHz and over a range of temperature from 303-413 K. In addition, AC conductivity values were calculated from the dielectric data and the conduction mechanism is discussed. The frequency-dependent conductivity behavior at different temperatures provides a qualitative description of the conduction mechanism. Also, differential scanning calorimetry (DSC) scans have been measured for the studied samples.
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页数：10
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