Phenothiazine derivatives, diketopyrrolopyrrole-based conjugated polymers: synthesis, optical and organic field effect transistor properties

被引:8
|
作者
Nhung Thanh Thi Truong [1 ]
Loc Tan Nguyen [1 ]
Huyen Le Thi Mai [1 ]
Bao Kim Doan [1 ]
Dat Hung Tran [1 ]
Khuong Tung Truong [1 ]
Viet Quoc Nguyen [1 ]
Nguyen, Le-Thu T. [2 ]
Mai Ha Hoang [3 ]
Toai Van Pham [4 ]
Vuong Mau Nguyen [4 ]
Tien Minh Huynh [5 ]
Tin Chanh Duc Doan [5 ]
Ha Tran Nguyen [1 ,2 ]
机构
[1] Vietnam Natl Univ VNU HCM, Ho Chi Minh City Univ Technol, Natl Key Lab Polymer & Composite Mat, 268 Ly Thuong Kiet,Dist 10, Ho Chi Minh City, Vietnam
[2] Vietnam Natl Univ VNU HCM, Ho Chi Minh City Univ Technol, Fac Mat Technol, 268 Ly Thuong Kiet,Dist 10, Ho Chi Minh City, Vietnam
[3] Vietnam Acad Sci & Technol, Inst Chem, 18 Hoang Quoc Viet, Hanoi, Vietnam
[4] Inst Propellants & Explosives, Gen Dept Def Ind, 192 Duc Giang, Hanoi, Vietnam
[5] Vietnam Natl Univ Ho Chi Minh City VNU HCM, Inst Nanotechnol INT, Linh Trung Ward, Community 6, Ho Chi Minh City, Vietnam
关键词
Phenothiazine; Donor - Acceptor conjugated polymers; Diketopyrrolopyrrole; Direct arylation polymerization; Organic solar cell; Organic field effect transistor; ENERGY-LEVEL MODULATION; ELECTROGENERATED CHEMILUMINESCENCE; ELECTRON-ACCEPTORS; SOLAR-CELLS; BAND-GAP; POLY(3-HEXYLTHIOPHENE); SEMICONDUCTOR; MOBILITY; BLEND;
D O I
10.1007/s10965-020-02199-x
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Novel donor-acceptor (D-A) conjugated polymers containing phenothiazine and diketopyrrolopyrrole derivatives were successfully synthesized via direct arylation polymerization using the palladium catalyst system. The C-N coupling reaction was performed for the synthesis of 4-(10H-phenothiazin-10-yl)-N,N-diphenylaniline (PDA) and 10-(pyren-1-yl)-10H-phenothiazine (PYP) as donor monomers. The D-A conjugated polymers synthesized by polymerization of PDA/PY with diketopyrrolopyrrole have been characterized via GPC,H-1 NMR, FTIR, XRD, DSC, PL and UV-Vis spectroscopy, and used for fabrication of organic field effect transistors.
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页数:13
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