Development of environmentally friendly coatings and paints using medium-chain-length poly(3-hydroxyalkanoates) as the polymer binder

被引:61
作者
van der Walle, GAM [1 ]
Buisman, GJH [1 ]
Weusthuis, RA [1 ]
Eggink, G [1 ]
机构
[1] DLO, ATO, Agrotechnol Res Inst, NL-6700 AA Wageningen, Netherlands
关键词
mcl-poly(3-hydroxyalkanoates); environmentally friendly paints; coatings;
D O I
10.1016/S0141-8130(99)00025-2
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Unsaturated medium-chain-length poly(3-hydroxyalkanoates) (mcl-PHAs) produced by Pseudomonas putida from linseed oil fatty acids (LOFA) and tall oil fatty acids (TOFA), were used as the polymer binder in the formulation of high solid alkyd-like paints. The relatively high concentration of unsaturated alkyl side chains incorporated into the PHA resins resulted in oxidative drying PHA paints having excellent coating properties. The homogeneously pigmented PHA coatings yielded high-gloss, smooth and strong films upon curing and showed an excellent flexibility, a good adhesion to different substrates, cohesive film properties and resistance to chipping. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:123 / 128
页数:6
相关论文
共 19 条
[1]  
Casini E, 1997, J ENVIRON POLYM DEGR, V5, P153
[2]   PHYSICAL-PROPERTIES OF BACTERIAL POLY((R)-3-HYDROXYALKANOATES) [J].
DEKONING, G .
CANADIAN JOURNAL OF MICROBIOLOGY, 1995, 41 :303-309
[3]  
Derksen J. T. P., 1994, Industrial Crops and Products, V3, P225, DOI 10.1016/0926-6690(94)00039-2
[4]  
DEWAARD P, 1993, J BIOL CHEM, V268, P315
[5]   THE ROLE OF FATTY-ACID BIOSYNTHESIS AND DEGRADATION IN THE SUPPLY OF SUBSTRATES FOR POLY(3-HYDROXYALKANOATE) FORMATION IN PSEUDOMONAS-PUTIDA [J].
EGGINK, G ;
DEWAARD, P ;
HUIJBERTS, GNM .
FEMS MICROBIOLOGY LETTERS, 1992, 103 (2-4) :159-163
[6]   FORMATION OF NOVEL POLY(HYDROXYALKANOATES) FROM LONG-CHAIN FATTY-ACIDS [J].
EGGINK, G ;
DEWAARD, P ;
HUIJBERTS, GNM .
CANADIAN JOURNAL OF MICROBIOLOGY, 1995, 41 :14-21
[7]  
EGGINK G, 1993, IND CROP PROD, V1, P157
[8]  
Hare C., 1994, PROTECTIVE COATINGS
[9]  
HOLBERG K, 1987, HIGH SOLIDS ALKYD RE
[10]   PSEUDOMONAS-PUTIDA KT2442 CULTIVATED ON GLUCOSE ACCUMULATES POLY(3-HYDROXYALKANOATES) CONSISTING OF SATURATED AND UNSATURATED MONOMERS [J].
HUIJBERTS, GNM ;
EGGINK, G ;
DEWAARD, P ;
HUISMAN, GW ;
WITHOLT, B .
APPLIED AND ENVIRONMENTAL MICROBIOLOGY, 1992, 58 (02) :536-544