An investigation of the bandgap and Urbach tail of vacuum-evaporated SnO2 thin films

被引:36
作者
Ikhmayies, Shadia J. [1 ]
Ahmad-Bitar, Riyad N. [2 ]
机构
[1] Al Isra Univ, Fac Informat Technol, Dept Basic Sci, Amman 16197, Jordan
[2] Univ Jordan, Fac Sci, Dept Phys, Amman 11942, Jordan
关键词
Thin films; Transparent conducting oxide; Optical bandgap energy; Urbach tail; ENERGY;
D O I
10.1016/j.renene.2012.01.045
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Tin oxide (SnO2) thin films with thickness in the range 100-600 nm were prepared by vacuum evaporation on glass substrates at ambient temperature. X-ray diffractograms showed that the films have poor crystallinity. The transmittance of the films was measured at room temperature in the wavelength range 290-1100 nm. The absorption coefficient was plotted as a function of photon's energy for films of different thickness and oscillatory behaviour was observed in the high energy side. This oscillatory behaviour which was found to increase with film thickness is evidence on the presence of nanoparticles. Direct and indirect optical bandgap energies were estimated and found to be decreasing with film thickness. Urbach tailing in the bandgap was observed and the width of the tail which is related with disorder and localized states was estimted and found to be decreasing with film thickness. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:143 / 146
页数:4
相关论文
共 12 条
[1]   Poole-Frenkel effect in nanocrystalline SnO2: F thin films prepared by a sol-gel dip-coating technique [J].
Banerjee, AN ;
Maity, R ;
Kundoo, S ;
Chattopadhyay, KK .
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE, 2004, 201 (05) :983-989
[2]   Surface reactivity of SnO2 obtained by sol-gel type condensation: Interaction with inert, combustible gases, vapour-phase H2O and air, as revealed by electron paramagnetic resonance spectroscopy [J].
Canevali, C ;
Chiodini, N ;
DiNola, P ;
Morazzoni, F ;
Scotti, R ;
Bianchi, CL .
JOURNAL OF MATERIALS CHEMISTRY, 1997, 7 (06) :997-1002
[3]  
Geraldo Viviany, 2003, Mat. Res., V6, P451
[4]  
Jonas Sundqvist, 2003, P 16 INT CVD C PAR F, V1, P511
[5]   BAND-GAP ENERGY AND URBACH TAIL STUDIES OF AMORPHOUS, PARTIALLY CRYSTALLINE AND POLYCRYSTALLINE TIN DIOXIDE [J].
MELSHEIMER, J ;
ZIEGLER, D .
THIN SOLID FILMS, 1985, 129 (1-2) :35-47
[6]   PERFORMANCE AND CHARACTERISTICS OF AL-PBS/SNO2-F SELECTIVE COATING SYSTEM FOR PHOTOTHERMAL ENERGY-CONVERSION [J].
MOHAMMAD, MT .
SOLAR ENERGY MATERIALS, 1990, 20 (04) :297-305
[7]   PROPERTIES OF FLUORINE-DOPED SNO2 FILMS PREPARED BY THE SPRAY PYROLYSIS TECHNIQUE [J].
MOHAMMAD, MT ;
ABDULGHAFOR, WA .
PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 1988, 106 (02) :479-484
[8]  
Montmeat P., 1999, THESIS ECOLE NATL SU
[9]   LOW-TEMPERATURE ELECTRICAL-CONDUCTIVITY AND OPTICAL-ABSORPTION EDGE OF ZNO FILMS PREPARED BY CHEMICAL-VAPOR-DEPOSITION [J].
NATSUME, Y ;
SAKATA, H ;
HIRAYAMA, T .
PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 1995, 148 (02) :485-495
[10]   Preparation and characterization of nitrogen-incorporated SnO2 films [J].
Pan, S. S. ;
Ye, C. ;
Teng, X. M. ;
Fan, H. T. ;
Li, G. H. .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2006, 85 (01) :21-24