Gold nanoparticles-catalyzed activation of 1,2-disilanes: hydrolysis, silyl protection of alcohols and reduction of tert-benzylic alcohols

被引：34
作者：
Gryparis, Charis [1 ]
Stratakis, Manolis [1 ]
机构：
[1] Univ Crete, Dept Chem, Iraklion 71003, Greece
来源：
CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 87期
关键词：
OXIDATION; ALKYNES; HEXAMETHYLDISILANE; PHENYLACETYLENE; HYDROSILANES; GOLD(III); PHENOLS; SILANES;
D O I：
10.1039/c2cc35116a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Gold nanoparticles supported on TiO2 catalyze under mild conditions the activation of a series of 1,2-disilanes towards hydrolysis and alcoholysis, with concomitant evolution of H-2 gas. For the case of tert-benzyl alcohols, the main or only pathway is reduction to the corresponding alkanes.
引用
收藏
页码：10751 / 10753
页数：3
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