Macrocycles with a phenothiazine core: synthesis, structural analysis, and electronic properties

被引：6

作者：

Medrut, Ilisca ^{[1
]}

Turdean, Raluca ^{[1
]}

Gropeanu, Radu ^{[1
]}

Pop, Flavia ^{[1
]}

Toupet, Loic ^{[2
]}

Hadade, Niculina D. ^{[1
]}

Bogdan, Elena ^{[1
]}

Grosu, Ion ^{[1
]}

机构：

[1] Univ Babes Bolyai, Supramol Organ & Organometall Chem Ctr SOOMCC, Cluj Napoca 400028, Romania

[2] Univ Rennes 1, UMR 6626, F-35042 Rennes, France

来源：

TETRAHEDRON LETTERS | 2013年 / 54卷 / 09期

关键词：

Phenothiazines; Macrocycles; X-ray molecular structure; C-H ... pi interactions; ES-HRMS investigations; 1ST SYNTHESIS; CATION; COMPLEXATION; POLYMERS;

D O I：

10.1016/j.tetlet.2012.12.068

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

New phenothiazine macrocycles with polyethyleneoxy chains were synthesized in good yields by reacting 10-ethyl-10H-3,7-di(3-hydroxyphenyl)phenothiazine with diiodurated or ditosylated polyethyleneglycols. Their structures were investigated by NMR spectroscopy and single crystal X-ray crystallography in the case of one compound. The electronic properties were determined by absorption spectroscopy and cyclic voltammetry and their complexation ability for alkali cations was investigated by ES-HRMS. (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：1107 / 1111

页数：5

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