A new catalyst for exclusive β-hydrosilylation of acrylonitrile

被引：5

作者：

Chauhan, M ^{[1
]}

Chauhan, BPS ^{[1
]}

Boudjouk, P ^{[1
]}

机构：

[1] N Dakota State Univ, Dept Chem, Ctr Main Grp Chem, Fargo, ND 58105 USA

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 22期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4039(99)00723-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Acrylonitrile and 2-chloroacrylonitrile react with trichlorosilane in the presence of cobalt chloride and an amine to give the beta-adduct in 75-95% yields under mild conditions. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：4127 / 4128

页数：2

共 8 条

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[6] HYDROSILYLATION OF ALPHA,BETA-UNSATURATED NITRILES AND ESTERS CATALYZED BY TRIS(TRIPHENYLPHOSPHINE)CHLORORHODIUM
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[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1976, 111 (01) : 43 - 60
[7] PREPARATION AND PROPERTIES OF BETA-CYANOETHYLTRICHLOROSILANE
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[J]. JOURNAL OF ORGANIC CHEMISTRY, 1959, 24 (12) : 1939 - 1942
[8] A NEW CATALYST FOR THE EFFICIENT AND SELECTIVE BETA-HYDROSILYLATION OF ACRYLONITRILE - EFFECT OF ULTRASOUND
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[J]. ORGANOMETALLICS, 1989, 8 (02) : 549 - 550

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