Rapid determination of the optical and redox properties of a metal-organic framework via in situ solid state spectroelectrochemistry

被引:105
作者
Usov, Pavel M. [1 ]
Fabian, Cesimiro [2 ]
D'Alessandro, Deanna M. [1 ]
机构
[1] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia
[2] Australian Nucl Sci & Technol Org, Inst Mat Engn, Lucas Heights, NSW, Australia
基金
澳大利亚研究理事会;
关键词
COORDINATION POLYMERS; CHEMISTRY; SPACE;
D O I
10.1039/c2cc30568b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The optical properties of [Zn-2(NDC)(2)(DPNI)](0/-/2-) (NDC = 2,7-naphthalene dicarboxylate, DPNI = N,N'-di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide), a redox-active metal-organic framework, have been examined using a simple and robust in situ solid state UV-Vis-NIR spectroelectrochemical technique.
引用
收藏
页码:3945 / 3947
页数:3
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