Ferroelectric and piezoelectric properties of [(Ba1-3x/2Bix)0.85Ca0.15](Ti0.90Zr0.10)O3 lead-free piezoelectric ceramics

被引:13
作者
Chen, Tao [1 ]
Zhang, Ting [1 ]
Zhou, Jifang [1 ]
Zhang, Jianwei [1 ]
Liu, Yuhong [1 ]
Wang, Guangchang [1 ]
机构
[1] Chengdu Med Coll, Teaching & Res Sect Phys, Chengdu 610083, Peoples R China
关键词
Ceramics; Electron microscopy; Piezoelectricity; TEMPERATURE; ELECTRODE;
D O I
10.1016/j.materresbull.2012.01.017
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Bismuth-modified barium calcium zirconate titanate ceramics [(Ba1-3x/2Bix)(0.85)Ca-0.15](Ti0.90Zr0.10)O-3 (BBCTZ) have been prepared by the conventional solid-state reaction method, and effects of Bi content on the electrical properties of BBCTZ ceramics were systematically investigated. BBCTZ ceramics endure a phase transition from the coexistence of rhombohedral and tetragonal phases, a tetragonal phase, to a cubic phase with increasing Bi content. The Curie temperature, the remanent polarization, and the dielectric loss of BBCTZ ceramics gradually decrease with increasing the Bi content. The BBCTZ ceramic with x = 0.0075 exhibits an optimum electrical behavior: d(33) similar to 361 pC/N and k(p) similar to 40.2%. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1104 / 1106
页数:3
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