Platinum-Supported Cerium-Doped Indium Oxide for Highly Sensitive Triethylamine Gas Sensing with Good Antihumidity

被引:97
|
作者
Zhou, Shiqiang [1 ]
Lu, QIngjie [1 ]
Chen, Mingpeng [2 ]
Li, Bo [1 ]
Wei, Haitang [1 ]
Zi, Baoye [1 ]
Zeng, Jiyang [1 ]
Zhang, Yumin [1 ]
Zhang, Jin [1 ]
Zhu, Zhongqi [1 ]
Liu, Qingju [1 ]
机构
[1] Yunnan Univ, Natl Ctr Int Res Photoelect & Energy Mat, Sch Mat & Energy, Yunnan Key Lab Micro Nano Mat & Technol, Kunming 650091, Yunnan, Peoples R China
[2] Univ Macau, Inst Appl Phys & Mat Engn, Macau 999078, Peoples R China
基金
中国国家自然科学基金;
关键词
In2O3; hollow hexagonal microtubes; gas sensor; triethylamine; high sensitivity and selectivity; antihumidity; SENSOR; NANOCOMPOSITE; DEGRADATION; MECHANISMS; DESIGN; CEO2; MOFS; NO2; AU;
D O I
10.1021/acsami.0c12363
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Triethylamine is extremely harmful to human health, and chronic inhalation can lead to respiratory and hematological diseases and eye lesions. Hence, it is essential to develop a triethylamine gas-sensing technology with high response, selectivity, and stability for use in healthcare and environmental monitoring. In this work, a simple and low-cost sensor based on the Pt- and Ce-modified In2O3 hollow structure to selectively detect triethylamine is developed. The experimental results reveal that the sensor based on 1% Pt/Ce12In exhibits excellent triethylamine-sensing performance, including its insusceptibility to water, reduced operating temperature, enhanced response, and superior long-term stability. This work suggests that the enhancement of sensing performance toward triethylamine can be attributed to the high relative contents of O-V and O-C, large specific surface area, catalytic effect, the electronic sensitization of Pt, and the reversible redox cycle properties of Ce. This sensor represents a unique and highly sensitive means to detect triethylamine, which shows great promise for potential applications in food safety inspection and environmental monitoring.
引用
收藏
页码:42962 / 42970
页数:9
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