Self-assembly of interlocked structures: Rotaxanes, polyrotaxanes and molecular necklaces

被引：23
|
作者：
Park, KM
Heo, J
Roh, SG
Jeon, YM
Whang, D
Kim, K
机构：
[1] Pohang Univ Sci & Technol, Ctr Smart Supramol, Pohang 790784, South Korea
[2] Pohang Univ Sci & Technol, Dept Chem, Pohang 790784, South Korea
来源：
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1999年 / 327卷
关键词：
self assembly; interlocked structures; metal ions; supramolecular chemistry;
D O I：
10.1080/10587259908026782
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Our recent work on construction of interlocked structures such as rotaxanes, polyrotaxanes and molecular necklaces using the principles of self assembly and coordination chemistry is described. In the synthesis of these structures, the barrel-shape molecule cucurbituril is used as a molecular "bead" and metal ions or metal complexes are used as "glue" or "angle connectors". Judicious choice of metal ions, counter ions and "strings" is important in order to construct the desired supramolecular structures.
引用
收藏
页码：65 / 70
页数：6
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