Activation of H2 by a Multiply Bonded Amido-Digermyne: Evidence for the Formation of a Hydrido-Germylene

被引：138

作者：

Hadlington, Terrance J. ^{[1
]}

Hermann, Markus ^{[2
]}

Li, Jiaye ^{[1
]}

Frenking, Gernot ^{[2
]}

Jones, Cameron ^{[1
]}

机构：

[1] Monash Univ, Sch Chem, Melbourne, Vic 3800, Australia

[2] Univ Marburg, Fachbereich Chem, D-35032 Marburg, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 39期

关键词：

DFT calculations; digermene; digermyne; hydride ligands; hydrogen activation; ISOMERIC FORMS; ALKYNE ANALOGS; STERIC BULK; COMPLEXES; REACTIVITY; CHEMISTRY; DIHYDROGEN; HYDROGEN; AMMONIA; DIMERS;

D O I：

10.1002/anie.201305689

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The long and the short of it. The first amido-digermyne to possess a short Ge-Ge multiple bond, [LGeGeL], has been prepared and shown to activate H 2 below 0 °C, thereby yielding the hydrido-digermene, [L(H)Geï£Ge(H)L]. This possesses a very long Geï£Ge bond. Spectroscopic and theoretical data indicate that the dimer dissociates in solution to give the two-coordinate hydrido-germylene, [:Ge(H)(L)]. L=N(Ar)(SiiPr3), Ar=2,6-[C(H)Ph2]2-4-iPrC 6H2. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：10199 / 10203

页数：5

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