Vanadocene-mediated ionization of water in the aqua species [H2O•B(C6F5)3]:: Structural characterization of the hydride and hydroxide complexes [CP2V(μ-OH)B(C6F5)3] and [CP2V(μ-OH)B(C6F5)3]

被引：14
|
作者：
Choukroun, R [1 ]
Lorber, C [1 ]
Vendier, L [1 ]
Lepetit, C [1 ]
机构：
[1] CNRS, UPR 8241, Chim Coordinat Lab, F-31077 Toulouse 04, France
来源：
ORGANOMETALLICS | 2006年 / 25卷 / 07期
关键词：
D O I：
10.1021/om050965x
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of Cp2V with B(C6F5)(3) in the presence of water leads to the hydride complex [Cp2V(mu-H)B(C6F5)(3)] (1) and the hydroxide complex [Cp2V(mu-OH)B(C6F5)(3)] (2), both of which have been characterized by, X-ray structure determinations. Both complexes are derived from the ionization of water in the presence of B(C6F5)(3).
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收藏
页码：1551 / 1553
页数：3
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