Vanadocene-mediated ionization of water in the aqua species [H2O•B(C6F5)3]:: Structural characterization of the hydride and hydroxide complexes [CP2V(μ-OH)B(C6F5)3] and [CP2V(μ-OH)B(C6F5)3]

被引：14
|
作者：
Choukroun, R [1 ]
Lorber, C [1 ]
Vendier, L [1 ]
Lepetit, C [1 ]
机构：
[1] CNRS, UPR 8241, Chim Coordinat Lab, F-31077 Toulouse 04, France
来源：
ORGANOMETALLICS | 2006年 / 25卷 / 07期
关键词：
D O I：
10.1021/om050965x
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of Cp2V with B(C6F5)(3) in the presence of water leads to the hydride complex [Cp2V(mu-H)B(C6F5)(3)] (1) and the hydroxide complex [Cp2V(mu-OH)B(C6F5)(3)] (2), both of which have been characterized by, X-ray structure determinations. Both complexes are derived from the ionization of water in the presence of B(C6F5)(3).
引用
收藏
页码：1551 / 1553
页数：3
相关论文
共 50 条
  • [21] Double Arylation of Acetylenedicarboxylate with B(C6F5)3
    Nakatsuka, Hiroshi
    Froehlich, Roland
    Kitamura, Masato
    Kehr, Gerald
    Erker, Gerhard
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2012, (08) : 1163 - 1166
  • [22] STEREOSPECIFIC POLYMERIZATION OF METHYL-METHACRYLATE INITIATED BY DIMETHYLZIRCONOCENE/B(C6F5)(3) (OR PH(3)CB(C6F5)(4))/ZN(C2H5)(2)
    SOGA, K
    DENG, H
    YANO, T
    SHIONO, T
    MACROMOLECULES, 1994, 27 (26) : 7938 - 7940
  • [23] Synthesis and Properties of [Cp2Ti(Me)(H2O)][B(C6F5)4]
    Dunlop-Briere, Alexandre F.
    Baird, Michael C.
    ORGANOMETALLICS, 2010, 29 (22) : 6117 - 6120
  • [24] Coordination of Al(C6F5)3vs. B(C6F5)3 on group 6 end-on dinitrogen complexes: chemical and structural divergences
    Escomel, Leon
    Martins, Frederico F.
    Vendier, Laure
    Coffinet, Anais
    Queyriaux, Nicolas
    Krewald, Vera
    Simonneau, Antoine
    CHEMICAL SCIENCE, 2024, 15 (29) : 11321 - 11336
  • [25] Reactions of transition-metal oxo complexes with B(C6F5)3: Crystal structures of [V{OB(C6P5)(3)}(acac)(2)], [Ti{OB(C6F5)(3)}(acac)(2)] and cis-[MoO{OB(C6F5)(3)}(acac)(2)] (acac equals acetylacetonate)
    Galsworthy, JR
    Green, MLH
    Muller, M
    Prout, K
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (08): : 1309 - 1313
  • [26] Synthesis and study of new binuclear compounds containing bridging (μ-CN)B(C6F5)3 and (μ-NC)B(C6F5)3 systems
    Vei, IC
    Pascu, SI
    Green, MLH
    Green, JC
    Schilling, RE
    Anderson, GDW
    Rees, LH
    DALTON TRANSACTIONS, 2003, (12) : 2550 - 2557
  • [27] Reactions of biologically inspired hydride sources with B(C6F5)3
    Wilkins, Lewis C.
    Santi, Nicolo
    Luk, Louis Y. P.
    Melen, Rebecca L.
    PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 2017, 375 (2101):
  • [28] Polymerization of 1-hexene by Cp*TiMe2(μ-Me)B(C6F5)3
    Murray, MC
    Baird, MC
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1998, 128 (1-3) : 1 - 4
  • [29] Reaction of AlR3 with [CPh3][B(C6F5)4]:: Facile degradation of [B(C6F5)4]- by transient "[AlR2]+"
    Bochmann, M
    Sarsfield, MJ
    ORGANOMETALLICS, 1998, 17 (26) : 5908 - 5912
  • [30] Syntheses, characterization, and crystal structures of the tetramethylammonium salts of the novel weakly coordinating anions [MeCO2{B(C6F5)3}]- and [MeCO2{B(C6F5)3}2]-
    Mitu, S
    Baird, MC
    CANADIAN JOURNAL OF CHEMISTRY, 2006, 84 (02) : 225 - 232
12345