Novel CsPbI3 QDs glass with chemical stability and optical properties

被引:80
作者
Liu, Sijin [1 ]
Luo, Yangkai [1 ]
He, Meiling [1 ]
Liang, Xiaojuan [1 ]
Xiang, Weidong [1 ]
机构
[1] Wenzhou Univ, Coll Chem & Mat Engn, Wenzhou 325035, Zhejiang, Peoples R China
关键词
Perovskite stability; CsPbI3 QDs glass; Melting quenching technique; Photoluminescence; HALIDE PEROVSKITE NANOCRYSTALS; PBSE QUANTUM DOTS; ANION-EXCHANGE; LEAD BROMIDE; ROOM-TEMPERATURE; WHITE LEDS; CL; PHOTOLUMINESCENCE; EFFICIENT; BR;
D O I
10.1016/j.jeurceramsoc.2017.10.012
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Bright and tunable photoluminescence properties for cesium lead halide (CsPbX3) quantum dots (QDs) hinder its application due to their easy degradation in humid and high temperature conditions. Here, we present a simple approach to fabricate a novel CsPbI3 QDs in zinc borosilicate glass through a conventional melting-quenching technique. CsPbI3 QDs glass exhibits high luminescent intensity, tunable narrow-band emission, including the same bandgap energies and emission spectra as CsPbI3 QDs solution, but the quantum yield and decay time show a reduction for the structure defect and electron-hole consist in CsPbI3 QDs glass. Moreover, different heat treated temperature effect the luminescence of CsPbI3 QDs glass. Absorption and photoluminescence spectra demonstrate that 540 degrees C is the ideal heat-treated temperature for CsPbI3 QDs glass. Consequently, this novel and stable CsPbI3 QDs glass reveals the promising candidate for all-inorganic perovskite in display and solid-state warm lighting source.
引用
收藏
页码:1998 / 2004
页数:7
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