Preparation and Luminescence Thermochromism of Tetranuclear Copper(I)-Pyridine-Iodide Clusters

被引：34

作者：

Parmeggiani, Fabio ^{[1
]}

Sacchetti, Alessandro ^{[1
]}

机构：

[1] Politecn Milan, Dept Chem Mat & Chem Engn G Natta, I-20131 Milan, Italy

来源：

JOURNAL OF CHEMICAL EDUCATION | 2012年 / 89卷 / 07期

关键词：

Upper-Division Undergraduate; Inorganic Chemistry; Laboratory Instruction; Hands-On Learning/Manipulatives; Coordination Compounds; Fluorescence Spectroscopy; Physical Properties; Synthesis; Transition Elements; UV-Vis Spectroscopy; PHOTOLUMINESCENCE PROPERTIES; FLUORESCENCE THERMOCHROMISM; PHOTOPHYSICAL PROPERTIES; AB-INITIO; COPPER(I); IODIDE; COMPLEXES; PYRIDINE; EMISSION;

D O I：

10.1021/ed200736b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A simple and straightforward synthesis of a tetranuclear copper(I) pyridine iodide cluster is described as a laboratory experiment for advanced inorganic chemistry undergraduate students. The product is used to demonstrate the fascinating and visually impressive phenomenon of luminescence thermochromism: exposed to long-wave UV light, the crystalline solid shows a bright yellow fluorescence at room temperature and an equally intense blue-violet fluorescence when cooled in liquid nitrogen. The procedure was also extended to several other pyridine ligands to allow students to synthesize different clusters and compare their photophysical behavior.

引用

页码：946 / 949

页数：4

共 24 条

[1]

Brauer G., 1963, HDB PREPARATIVE INOR, V2, P1007

[2] Preparation and Properties of a Spectacular Thermochromic Solid [J].

Bukleski, Miha ;

Petrusevski, Vladimir M. .

JOURNAL OF CHEMICAL EDUCATION, 2009, 86 (01) :30-30

[3] Luminescence response of the solid state polynuclear copper(I) iodide materials [CuI(4-picoline)]x to volatile organic compounds [J].

Cariati, E ;

Bourassa, J ;

Ford, PC .

CHEMICAL COMMUNICATIONS, 1998, (16) :1623-1624

[4]

Changyun C., 2000, J CHEM EDUC, V77, P1206

[5] THERMOCHROMIC TETRACHLOROCUPRATE(II) - AN ADVANCED INTEGRATED LABORATORY EXPERIMENT [J].

CHOI, S ;

LARRABEE, JA .

JOURNAL OF CHEMICAL EDUCATION, 1989, 66 (09) :774-776

[6] Preparation and Thermochromic Properties of Copper(II)-N,N-Diethylethylenediamine Complexes [J].

Cui, Ai-Li ;

Chen, Xi ;

Sun, Long ;

Wei, Jing-Zhi ;

Yang, Jin ;

Kou, Hui-Zhong .

JOURNAL OF CHEMICAL EDUCATION, 2011, 88 (03) :311-312

[7] Electronic transitions involved in the absorption spectrum and dual luminescence of tetranuclear cubane [Cu4I4(pyridine)4] cluster:: a density functional theory/time-dependent density functional theory investigation [J].

De Angelis, Filippo ;

Fantacci, Simona ;

Sgamellotti, Antonio ;

Cariati, Elena ;

Ugo, Renato ;

Ford, Peter C. .

INORGANIC CHEMISTRY, 2006, 45 (26) :10576-10584

[8] CONTINUOUS AND DISCONTINUOUS THERMOCHROMISM OF COPPER(II) AND NICKEL(II) COMPLEXES WITH N,N-DIETHYLETHYLENEDIAMINE [J].

FABBRIZZI, L ;

MICHELONI, M ;

PAOLETTI, P .

INORGANIC CHEMISTRY, 1974, 13 (12) :3019-3021

[9] PHOTOCHEMICAL AND PHOTOPHYSICAL PROPERTIES OF TETRANUCLEAR AND HEXANUCLEAR CLUSTERS OF METALS WITH D10 AND S2 ELECTRONIC CONFIGURATIONS [J].

FORD, PC ;

VOGLER, A .

ACCOUNTS OF CHEMICAL RESEARCH, 1993, 26 (04) :220-226

[10] Photoluminescence properties of multinuclear copper(I) compounds [J].

Ford, PC ;

Cariati, E ;

Bourassa, J .

CHEMICAL REVIEWS, 1999, 99 (12) :3625-3647

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