Reactivity of carbon dioxide in hydrofluoroethers: a facile access to cyclic carbonates

被引：10

作者：

Mamone, Marius ^{[1
]}

Milcent, Thierry ^{[1
]}

Crousse, Benoit ^{[1
]}

机构：

[1] Univ Paris 11, BioCIS, CNRS, Fac Pharm,LabEx LERMIT, F-92290 Chatenay Malabry, France

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 64期

关键词：

ORGANIC CARBONATES; CO2; PERFLUOROCARBONS; TRANSFORMATION; EFFICIENT; FIXATION; CATALYST;

D O I：

10.1039/c5cc03896k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The high solubility of CO2 in hydrofluoroethers led to various cyclic carbonates with excellent selectivities and yields. The fluorinated phase increased the amount of CO2 in contact with the reagents. Reactions could be realized under mild conditions at 80 degrees C, under atmospheric pressure or under 5 bar.

引用

页码：12736 / 12739

页数：4

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