A unique six-membered chelated iridium complex

被引：4

作者：

Ammermann, Sven ^{[1
]}

Daniliuc, Constantin ^{[2
]}

Jones, Peter G. ^{[2
]}

du Mont, Wolf-Walther ^{[2
]}

Kowalsky, Wolfgang ^{[1
]}

Johannes, Hans-Hermann ^{[1
]}

机构：

[1] Tech Univ Carolo Wilhelmina Braunschweig, Labor Elektroopt Inst Hochfrequenztech, D-38023 Braunschweig, Germany

[2] Tech Univ Carolo Wilhelmina Braunschweig, Inst Anorgan & Analyt Chem, D-38023 Braunschweig, Germany

来源：

DALTON TRANSACTIONS | 2008年 / 31期

关键词：

D O I：

10.1039/b807735p

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of 2-(3-methylbiphenyl-2-yl) pyridine with IrCl3 center dot nH(2)O in the presence of water incorporates a tightly bonded CO at the iridium center; in the subsequent reaction with picolinic acid a complex revealing an unusual CH activation of a methyl group is formed.

引用

收藏

页码：4095 / 4098

页数：4

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