Liquid-Liquid Equilibrium of Water+1-Propanol or 1-Butanol + Dibutyl Ether Ternary Systems: Measurements and Correlation at Three Temperatures

被引：3
|
作者：
Feng, Wanxia [1 ]
Zhang, Quanzhou [1 ]
Chen, Yao [1 ]
机构：
[1] Jinan Univ, Dept Chem, Guangzhou 510632, Guangdong, Peoples R China
来源：
JOURNAL OF SOLUTION CHEMISTRY | 2018年 / 47卷 / 03期
关键词：
Liquid-liquid equilibrium; Dibutyl ether; Modified UNIQUAC model; Extended UNIQUAC model; DIBUTYL ETHER; DIFFERENT TEMPERATURES; AQUEOUS-SOLUTIONS; UNIQUAC MODEL; PLUS WATER; 2-PROPANOL; EXTRACTION; MIXTURES; ALCOHOLS; LLE;
D O I：
10.1007/s10953-018-0733-0
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Liquid-liquid equilibrium (LLE) date for the ternary systems of {water + 1-propanol + dibutyl ether (DBE)} and (water + 1-butanol + DBE) were determined at T = (293.15, 303.15, 308.15) K under atmospheric pressure. Distribution coefficients and separation factors of 1-propanol in the mixtures were calculated and are discussed. The influence of temperature on the liquid phase regions was analyzed. In addition, the experimental values were correlated well with the modified and extended UNIQUAC models; the modified UNIQUAC model represents the data better than the extended UNIQUAC model.
引用
收藏
页码：498 / 510
页数：13
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