Effect of M-doping (M = Fe, V) on the photocatalytic activity of nanorod rutile TiO2 for Congo red degradation under the sunlight

被引:29
|
作者
Melghit, Khaled [1 ]
Al-Shukeili, Odheiba S. [1 ]
Ai-Amri, Issa [2 ]
机构
[1] Sultane Qaboos Univ, Dept Chem, Coll Sci, Al Khoud 123, Oman
[2] Sultane Qaboos Univ, Coll Med & Hlth Sci, Electron Microscopy Unit, Al Khoud 123, Oman
关键词
Photodegradation; Congo red; Fe-doped TiO2; V-doped TiO2; QUANTUM-SIZED TIO2; METAL-ION DOPANTS; METHYLENE-BLUE; TITANIUM-OXIDE; CATALYSTS;
D O I
10.1016/j.ceramint.2007.12.009
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Nanorods TiO2, Fe-TiO2 (3 and 2 at.% Fe), V-TiO2 (5 at.% V) were prepared by a low temperature method and characterized by powder X-ray diffraction, thermal analysis, transmission electron microscope and BTE surface area analysis. The as-prepared samples were evaluated as catalysts for photodegradation of Congo red aqueous solution under the sunlight. Nanorods Fe-doped TiO2 shows higher adsorption and also higher photocatalytic degradation of Congo red solution compared to pure nanorods TiO2 rutile. A higher activity is obtained when the amount of doped Fe is 2 at. %, compared to 3 at.%. However, nanorods V-TiO2 does not show neither adsorption nor photodegradation activity of Congo red solution. (C) 2008 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
引用
收藏
页码:433 / 439
页数:7
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