A heterotriangulene polymer for air-stable organic field-effect transistors

被引：27
|
作者：
Schmoltner, Kerstin [1 ]
Schluetter, Florian [2 ]
Kivala, Milan [2 ]
Baumgarten, Martin [2 ]
Winkler, Stefanie [3 ,4 ]
Trattnig, Roman [1 ]
Koch, Norbert [3 ,4 ]
Klug, Andreas [1 ]
List, Emil J. W. [1 ,5 ]
Muellen, Klaus [2 ]
机构：
[1] NanoTecCtr Weiz Forsch Gesell MbH, A-8160 Weiz, Austria
[2] Max Planck Inst Polymer Res, D-55021 Mainz, Germany
[3] Helmholtz Zentrum Berlin Mat & Energie GmbH Elekt, D-12489 Berlin, Germany
[4] Humboldt Univ, Inst Phys, D-12489 Berlin, Germany
[5] Graz Univ Technol, Inst Solid State Phys, A-8010 Graz, Austria
来源：
POLYMER CHEMISTRY | 2013年 / 4卷 / 20期
关键词：
THIN-FILM TRANSISTORS; CHARGE-CARRIER MOBILITY; CONJUGATED POLYMERS; DEVICES; HOLE; SEMICONDUCTORS; PERFORMANCE; INSULATORS; COPOLYMERS; ELECTRODES;
D O I：
10.1039/c3py00089c
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
We report on a novel air-stable p-type heterotriangulene polymer (PTA) for large-area organic field-effect transistor (OFET) applications. The newly synthesized amorphous organic semiconductor was characterized concerning morphological, optical, electrical and interface related properties and revealed a saturation mobility of similar to 4.2 x 10(-3) cm(2) V-1 s(-1) and an on/off current ratio of similar to 10(5) in bottom-gate/bottom-contact (BG/BC) OFETs. The influence of several interface modifications was investigated in order to optimize the device performance. PTA FETs exhibited excellent air stability over several months and a superior performance compared to the widely used poly(3-hexylthiophene)-based OFETs. Moreover, we show that hydrochloric acid in chloroform leads to protonation of the nitrogen atoms on the PTA polymer, resulting in a significant change of the electrical characteristics of OFETs.
引用
收藏
页码：5337 / 5344
页数：8
相关论文
共 50 条
  • [1] Air-stable ambipolarity of nanofibril polymer semiconductors in staggered organic field-effect transistors
    Jun-Gu Park
    Jun-Woo Park
    Kang-Jun Baeg
    Journal of the Korean Physical Society, 2021, 79 : 468 - 476
  • [2] Air-stable ambipolarity of nanofibril polymer semiconductors in staggered organic field-effect transistors
    Park, Jun-Gu
    Park, Jun-Woo
    Baeg, Kang-Jun
    JOURNAL OF THE KOREAN PHYSICAL SOCIETY, 2021, 79 (05) : 468 - 476
  • [3] Air-stable ambipolar organic field-effect transistors based on naphthalenediimide-diketopyrrolopyrrole copolymers
    Wang, Ping
    Li, Hui
    Gu, Chunling
    Dong, Huanli
    Xu, Zhenzhen
    Fu, Hongbing
    RSC ADVANCES, 2015, 5 (25) : 19520 - 19527
  • [4] Optimization of thieno[2,3-b]thiophene derivatives for air-stable organic field-effect transistors
    Oh, Seongjin
    Kang, Hyowon
    Chen, Ming-Chou
    Kim, Choongik
    Seo, Sungyong
    DYES AND PIGMENTS, 2025, 235
  • [5] Solution processed air-stable p-channel organic crystal field-effect transistors of Aminobenzodifuranone
    Deng, Zhifeng
    Yang, Kun
    Li, Leiquan
    Bao, Weiwei
    Hao, Xiaoli
    Ai, Taotao
    Kou, Kaichang
    DYES AND PIGMENTS, 2018, 151 : 173 - 178
  • [6] Hydrogen-Bonded Semiconducting Pigments for Air-Stable Field-Effect Transistors
    Glowacki, Eric Daniel
    Irimia-Vladu, Mihai
    Kaltenbrunner, Martin
    Gasiorowski, Jacek
    White, Matthew S.
    Monkowius, Uwe
    Romanazzi, Giuseppe
    Suranna, Gian Paolo
    Mastrorilli, Piero
    Sekitani, Tsuyoshi
    Bauer, Siegfried
    Someya, Takao
    Torsi, Luisa
    Sariciftci, Niyazi Serdar
    ADVANCED MATERIALS, 2013, 25 (11) : 1563 - 1569
  • [7] Acetylenic spacers in phenylene end-substituted oligothiophene core for highly air-stable organic field-effect transistors
    Diallo, Abdou Karim
    Videlot-Ackermann, Christine
    Marsal, Philippe
    Brisset, Hugues
    Fages, Frederic
    Kumagai, Atsufumi
    Yoshimoto, Noriyuki
    Serein-Spirau, Francoise
    Lere-Porte, Jean-Pierre
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2010, 12 (15) : 3845 - 3851
  • [8] Flexible air-stable three-dimensional polymer field-effect transistors with high output current density
    Nakayama, K.
    Ou-Yang, W.
    Uno, M.
    Osaka, I.
    Takimiya, K.
    Takeya, J.
    ORGANIC ELECTRONICS, 2013, 14 (11) : 2908 - 2915
  • [9] Isomeric dibenzooctazethrene diradicals for high-performance air-stable organic field-effect transistors
    Zong, Chaoyang
    Yang, Shuyuan
    Sun, Yajing
    Zhang, Lifeng
    Hu, Jinlian
    Hu, Wenping
    Li, Rongjin
    Sun, Zhe
    CHEMICAL SCIENCE, 2022, 13 (38) : 11442 - 11447
  • [10] Novel Semiconducting Quinone for Air-Stable n-Type Organic Field-Effect Transistors
    Mamada, Masashi
    Kumaki, Daisuke
    Nishida, Jun-ichi
    Tokito, Shizuo
    Yamashita, Yoshiro
    ACS APPLIED MATERIALS & INTERFACES, 2010, 2 (05) : 1303 - 1307
12345