First high resolution analysis of the v3 band of the 36SF6 isotopologue

被引：6
作者：
Faye, M. [1 ,2 ]
Manceron, L. [1 ,3 ]
Roy, P. [1 ]
Boudon, V. [4 ]
Loete, M. [4 ]
机构：
[1] AILES Beamline, Synchrotron SOLEIL, F-91192 Lorme Des Merisiers, St Aubin, France
[2] Univ Paris Est Creteil, Lab Interuniv Syst Atmospher, Val Marne 61 Ave Gen Gaulle, F-94010 Creteil, France
[3] Univ Paris 06, CNRS, UMR 8233, Monaris, 4 Pl Jussieu Case 49, F-75252 Paris, France
[4] Univ Bourgogne Franche Comte, CNRS, UMR 6303, Lab Interdisciplinaire Carrot Bourgogne, 9 Ave Alain Savory,BP 47870, F-21078 Dijon, France
来源：
JOURNAL OF MOLECULAR SPECTROSCOPY | 2018年 / 346卷
关键词：
NU(3) BAND; SF6; SPECTRA; MODEL;
D O I：
10.1016/j.jms.2018.01.002
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
The v(3) band of the (SF6)-S-36 isotopologue has been recorded in natural abundance (0.02%) at 153 K-temperature with doppler limited resolution, using a Fourier transform spectrometer. For the first time, the high resolution analysis of this band is performed thanks to the Dijon tensorial formalism model. The effective Hamiltonian parameters are determined and the interest of studying rare SF6 isotopologues is discussed. (C) 2018 Elsevier Inc. All rights reserved.
引用
收藏
页码：23 / 26
页数：4
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