Thienyl-BOPHY dyes as promising templates for bulk heterojunction solar cells

被引：45
作者：
Mirloup, A. [1 ]
Huaulme, Q. [1 ]
Leclerc, N. [2 ]
Leveque, P. [3 ]
Heiser, T. [3 ]
Retailleau, P. [4 ]
Ziessel, R. [1 ]
机构：
[1] ECPM, Inst Chim & Proc Energie Environm & Sante, Lab Chim Mol & Spect Avancees ICPEES LCOSA, CNRS,UMR 7515, F-67087 Strasbourg 02, France
[2] ECPM, ICPEES, Dept Ingn Polymere, UMR 7515, F-67087 Strasbourg 02, France
[3] Univ Strasbourg, CNRS, UMR 7357, Lab Sci Ingn Informat & Imagerie ICube, F-67037 Strasbourg 02, France
[4] CNRS, Inst Chim Subst Nat, F-91198 Gif Sur Yvette, France
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 79期
关键词：
FIELD-EFFECT TRANSISTORS; HIGHLY FLUORESCENT; EFFICIENCY;
D O I：
10.1039/c5cc05095b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis and characterization of bis(difluoroboryl)-1,2-bis-((1H-pyrrol-2-yl) methylene) hydrazone functionalized with two lateral vinyl-thienyl modules and exhibiting strong absorption in the 400-800 nmwindow in thin films are reported. Bulk heterojunction solar cells assembled with these dyes and a fullerene derivative (PC71BM), using very small quantities of the additive diiodooctane, give a power conversion efficiency as high as 4.3% with short-circuit current values of 10.9 mA cm(-2), an open-circuit voltage of 0.7 V and external quantum efficiencies higher than 70% over a broad range of wavelengths (580 to 720 nm).
引用
收藏
页码：14742 / 14745
页数：4
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