Thienyl-BOPHY dyes as promising templates for bulk heterojunction solar cells

被引：45

作者：

Mirloup, A. ^{[1
]}

Huaulme, Q. ^{[1
]}

Leclerc, N. ^{[2
]}

Leveque, P. ^{[3
]}

Heiser, T. ^{[3
]}

Retailleau, P. ^{[4
]}

Ziessel, R. ^{[1
]}

机构：

[1] ECPM, Inst Chim & Proc Energie Environm & Sante, Lab Chim Mol & Spect Avancees ICPEES LCOSA, CNRS,UMR 7515, F-67087 Strasbourg 02, France

[2] ECPM, ICPEES, Dept Ingn Polymere, UMR 7515, F-67087 Strasbourg 02, France

[3] Univ Strasbourg, CNRS, UMR 7357, Lab Sci Ingn Informat & Imagerie ICube, F-67037 Strasbourg 02, France

[4] CNRS, Inst Chim Subst Nat, F-91198 Gif Sur Yvette, France

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 79期

关键词：

FIELD-EFFECT TRANSISTORS; HIGHLY FLUORESCENT; EFFICIENCY;

D O I：

10.1039/c5cc05095b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and characterization of bis(difluoroboryl)-1,2-bis-((1H-pyrrol-2-yl) methylene) hydrazone functionalized with two lateral vinyl-thienyl modules and exhibiting strong absorption in the 400-800 nmwindow in thin films are reported. Bulk heterojunction solar cells assembled with these dyes and a fullerene derivative (PC71BM), using very small quantities of the additive diiodooctane, give a power conversion efficiency as high as 4.3% with short-circuit current values of 10.9 mA cm(-2), an open-circuit voltage of 0.7 V and external quantum efficiencies higher than 70% over a broad range of wavelengths (580 to 720 nm).

引用

页码：14742 / 14745

页数：4

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