Novel gas holdup correlation for slurry bubble column reactors operated in the homogeneous regime

被引:40
作者
Goetz, Manuel [1 ]
Lefebvre, Jonathan [2 ]
Moers, Friedemann [1 ]
Ortloff, Felix [1 ]
Reimert, Rainer [2 ]
Bajohr, Siegfried [2 ]
Kolb, Thomas [1 ,2 ]
机构
[1] Karlsruhe Inst Technol, Engler Bunte Inst, DVGW Forsch Steile, Engler Bunte Ring 1, D-76131 Karlsruhe, Germany
[2] Karlsruhe Inst Technol, Engler Bunte Inst, Fuel Technol, Engler Bunte Ring 1, D-76131 Karlsruhe, Germany
关键词
Bubble column; Slurry bubble column reactor; Gas holdup correlation; Homogeneous regime; Solids' influence; Hydrodynamics; MASS-TRANSFER COEFFICIENTS; FINE PORE SPARGER; ELEVATED PRESSURES; DESIGN PARAMETERS; METHANOL SYNTHESIS; LIQUID PROPERTIES; INTERFACIAL AREA; ORGANIC LIQUIDS; IONIC LIQUIDS; VISCOUS MEDIA;
D O I
10.1016/j.cej.2016.09.101
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The gas holdup is an important parameter for the design of slurry bubble columns. However, there is no correlation in literature to calculate the gas holdup of such reactors for industrially relevant conditions if the reactor is operated in the homogeneous regime. In this article, a novel correlation for calculating the gas holdup in the homogeneous and in the pseudo-homogeneous regimes is proposed. The correlation takes the relevant parameters into account: gas, liquid, and solid properties, sparger design, reactor diameter, and gas velocity. The correlation is also applicable for systems operated at elevated pressure and temperature. The correlation is based on 1199 data points, and it was developed by using the method of least squares. About two thirds of the data used were taken from literature (more than 20 research papers). The data from literature were carefully checked for confidence before using them for the correlation. > 90 % of the data points are covered by the new correlation with a relative error of less than 30 %, the standard deviation is 17.8 % and the averaged relative error is 9.5 %. Finally, the correlation was successfully validated with measurements which were not used to fit the correlation. An Excel file for using the developed correlation can be found in the Supplementary material. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:1209 / 1224
页数:16
相关论文
共 85 条
[1]   GAS HOLDUP AND VOLUMETRIC MASS-TRANSFER COEFFICIENT IN BUBBLE COLUMNS - EFFECTS OF LIQUID PROPERTIES [J].
AKITA, K ;
YOSHIDA, F .
INDUSTRIAL & ENGINEERING CHEMISTRY PROCESS DESIGN AND DEVELOPMENT, 1973, 12 (01) :76-80
[2]   Bubble columns with fine pore sparger and non-Newtonian liquid phase: Prediction of gas holdup [J].
Anastasiou, A. D. ;
Passos, A. D. ;
Mouza, A. A. .
CHEMICAL ENGINEERING SCIENCE, 2013, 98 :331-338
[3]   Effect of organic surfactant additives on gas holdup in the pseudo-homogeneous regime in bubble columns equipped with fine pore sparger [J].
Anastasiou, A. D. ;
Kazakis, N. A. ;
Mouza, A. A. ;
Paras, S. V. .
CHEMICAL ENGINEERING SCIENCE, 2010, 65 (22) :5872-5880
[4]  
[Anonymous], 2006, BILDUNG BEWEGUNG TRO, P1099
[5]  
[Anonymous], 2013, VDI-warmeatlas
[6]  
Basha O.M., 2015, INT J CHEM REACTOR E
[7]   MASS-TRANSFER IN GAS-LIQUID SLURRY REACTORS [J].
BEENACKERS, AACM ;
VANSWAAIJ, WPM .
CHEMICAL ENGINEERING SCIENCE, 1993, 48 (18) :3109-3139
[8]   Novel correlations for gas holdup in large-scale slurry bubble column reactors operating under elevated pressures and temperatures [J].
Behkish, A ;
Lemoine, R ;
Oukaci, R ;
Morsi, BI .
CHEMICAL ENGINEERING JOURNAL, 2006, 115 (03) :157-171
[9]  
Behkish A., 2005, THESIS
[10]   Gas holdup and bubble size behavior in a large-scale slurry bubble column reactor operating with an organic liquid under elevated pressures and temperatures [J].
Behkish, Arsam ;
Lemoine, Romain ;
Sehabiague, Laurent ;
Oukaci, Rachid ;
Morsi, Badie I. .
CHEMICAL ENGINEERING JOURNAL, 2007, 128 (2-3) :69-84