Solvent effects in epoxidation of fatty acid methyl esters (FAMEs) by hydrogen peroxide on a TS-1 heterogeneous catalyst is studied for the first time. It is found that the catalytic activity of TS-1 (titanium silicalite) is significantly affected by the polarity of the solvent and its proton-donor-acceptor properties. The highest activity and selectivity is ensured by the use of solvents that are not donors of hydrogen bonds. The best results were achieved when acetonitrile was used as a solvent: the conversion of FAMEs after 6 h was 77%, and the selectivity to epoxide was 61%.
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Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China
Univ Chinese Acad Sci, Beijing 100049, Peoples R ChinaChinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China
Jiao, Weiyong
He, Yue
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Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R ChinaChinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China
He, Yue
Li, Junfen
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Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R ChinaChinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China
Li, Junfen
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Wang, Jianguo
Tatsumi, Takashi
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Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, JapanChinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China
Tatsumi, Takashi
Fan, Weibin
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Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R ChinaChinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China
机构:
Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China
Univ Chinese Acad Sci, Beijing 100049, Peoples R ChinaChinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China
Jiao, Weiyong
He, Yue
论文数: 0引用数: 0
h-index: 0
机构:
Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R ChinaChinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China
He, Yue
Li, Junfen
论文数: 0引用数: 0
h-index: 0
机构:
Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R ChinaChinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China
Li, Junfen
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Wang, Jianguo
Tatsumi, Takashi
论文数: 0引用数: 0
h-index: 0
机构:
Tokyo Inst Technol, Chem Resources Lab, Midori Ku, Yokohama, Kanagawa 2268503, JapanChinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China
Tatsumi, Takashi
Fan, Weibin
论文数: 0引用数: 0
h-index: 0
机构:
Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R ChinaChinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Peoples R China