Structural Characterization, Luminescence Behavior and Antimicrobial Study of a Zinc Coordination Polymer Based on Bis(imidazole) Ligand

被引：0
作者：
Zhou Xian-Li [1 ]
Zhang Bing-Jun [1 ]
Wang Cui-Juan [1 ]
Huang Shuai [1 ]
Qiu Guang-Mei [1 ]
Wang Yao-Yu [2 ]
机构：
[1] SW JiaoTong Univ, Sch Life Sci & Bioengn, Dept Chem & Chem Engn, Chengdu 610031, Peoples R China
[2] NW Univ Xian, Dept Chem, Minist Educ, Key Lab Synthet & Nat Funct Mol Chem, Xian 710069, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2012年 / 28卷 / 08期
关键词：
1,1 '-(1,4-Butanediyl)bis(imidazole); coordination polymer; fluorescence spectrum; antimicrobial activity; METHYLENEDIISOPHTHALIC ACID; AROMATIC POLYCARBOXYLATE; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURES; FRAMEWORKS; CARBOXYLATE; COPPER(II); COMPLEXES; 1D; FLUORESCENCE;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A coordination polymer based on zinc(II) and mixed ligands [Zn(oxa)(bbi)](n) (1) (oxa=oxalate anion, bbi= 1,1'-(1,4-butanediyl)bis (imidazole)), has been prepared and characterized by single-crystal X-ray diffraction. The structure of polymer 1 presents an unique two-dimensional (2D) layer structure with (4,4) topology in the presence of meso-helical chains and a three-dimensional (3D) network distorted with large channels. In addition, moderate fluorescent emission in the solid state at room temperature was observed in the Zn1-containing polymeric compound 1. And antimicrobial activity of the compound has been investigated. CCDC: 842497.
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页码：1736 / 1742
页数：7
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