Strategies for binding multiple guests in metal-organic cages

被引：336

作者：

Rizzuto, Felix J. ^{[1
]}

von Krbek, Larissa K. S. ^{[1
]}

Nitschke, Jonathan R. ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Cambridge, England

来源：

NATURE REVIEWS CHEMISTRY | 2019年 / 3卷 / 04期

基金：

英国工程与自然科学研究理事会; 欧洲研究理事会;

关键词：

M2L4 MOLECULAR CAPSULE; DIELS-ALDER REACTIONS; SUPRAMOLECULAR HOST; COORDINATION CAGES; CRYSTALLOGRAPHIC OBSERVATION; SOLVENT REORGANIZATION; COBALT-PORPHYRIN; NEUTRAL GUESTS; DRIVING-FORCE; ANION-BINDING;

D O I：

10.1038/s41570-019-0085-3

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The binding of multiple guests by a single entity can lead to new modes of host-guest interactions and thus new applications in, for example, catalysis and sensing. With the aim of developing modular systems that can promote and adapt to allosteric binding events, this Review explores current strategies used to bind multiple guests in the central and peripheral environments of coordination cages. The structural and functional consequences of multi-guest binding are examined, highlighting the methods by which guest configurations involving more than one copy of the same guest, as well as multiple different guests, may be designed. We thus aim to provide new methodological insights and tools into the design of new capsules for multiple guest-specific binding events, towards the development of guest-guest chemistry within synthetic systems.

引用

收藏

页码：204 / 222

页数：19

相关论文

共 186 条

[11]

2-K

[12] A Pd24 Pregnant Molecular Nanoball: Self-Templated Stellation by Precise Mapping of Coordination Sites [J].

Bhat, Imtiyaz Ahmad ;

Samanta, Dipak ;

Mukherjee, Partha Sarathi .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (29) :9497-9502

[13] Release of High-Energy Water as an Essential Driving Force for the High-Affinity Binding of Cucurbit[n]urils [J].

Biedermann, Frank ;

Uzunova, Vanya D. ;

Scherman, Oren A. ;

Nau, Werner M. ;

De Simone, Alfonso .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (37) :15318-15323

[14] A Self-Assembled [FeII12L12] Capsule with an Icosahedral Framework [J].

Bilbeisi, Rana A. ;

Ronson, Tanya K. ;

Nitschke, Jonathan R. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (34) :9027-9030

[15] Supramolecular Catalysis in Metal-Ligand Cluster Hosts [J].

Brown, Casey J. ;

Toste, F. Dean ;

Bergman, Robert G. ;

Raymond, Kenneth N. .

CHEMICAL REVIEWS, 2015, 115 (09) :3012-3035

[16] Ultra-large supramolecular coordination cages composed of endohedral Archimedean and Platonic bodies [J].

Byrne, Kevin ;

Zubair, Muhammad ;

Zhu, Nianyong ;

Zhou, Xiao-Ping ;

Fox, Daniel S. ;

Zhang, Hongzhou ;

Twamley, Brendan ;

Lennox, Matthew J. ;

Duren, Tina ;

Schmitt, Wolfgang .

NATURE COMMUNICATIONS, 2017, 8

[17] The Promise of Self-Assembled 3D Supramolecular Coordination Complexes for Biomedical Applications [J].

Casini, Angela ;

Woods, Benjamin ;

Wenzel, Margot .

INORGANIC CHEMISTRY, 2017, 56 (24) :14715-14729

[18] Supramolecular Coordination: Self-Assembly of Finite Two- and Three-Dimensional Ensembles [J].

Chakrabarty, Rajesh ;

Mukherjee, Partha Sarathi ;

Stang, Peter J. .

CHEMICAL REVIEWS, 2011, 111 (11) :6810-6918

[19] Self-assembled metallocycles with two interactive binding domains [J].

Chang, SY ;

Jang, HY ;

Jeong, KS .

CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (17) :4358-4366

[20] Luminescent, Enantiopure, Phenylatopyridine Iridium-Based Coordination Capsules [J].

Chepelin, Oleg ;

Ujma, Jakub ;

Wu, Xiaohua ;

Slawin, Alexandra M. Z. ;

Pitak, Mateusz B. ;

Coles, Simon J. ;

Michel, Julien ;

Jones, Anita C. ;

Barran, Perdita E. ;

Lusby, Paul J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (47) :19334-19337

← 1 2 3 4 5 6 7 8 9 10 →