Chemo-enzymatic Baeyer-Villiger oxidation of cyclopentanone and substituted cyclopentanones

被引：35

作者：

Rios, Maria Yolanda ^{[1
]}

Salazar, Enrique ^{[1
]}

Olivo, Horacio F. ^{[1
]}

机构：

[1] Univ Iowa, Div Med & Nat Prod Chem, Iowa City, IA 52242 USA

来源：

JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC | 2008年 / 54卷 / 3-4期

基金：

美国国家科学基金会;

关键词：

chemo-enzymatic oxidation; Candida antarctica lipase-B; Baeyer-Villiger oxidation; trans-esterification;

D O I：

10.1016/j.molcatb.2007.12.012

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Chemo-enzymatic oxidation of cyclopentanones and substituted cyclopentanones to the corresponding delta-valerolactones was investigated employing catalytic a mount of Candida antarctica lipase-B in ethyl acetate and employing urea-hydrogen peroxide its the oxidant. In contrast to the smooth oxidation of cyclohexanones to the corresponding epsilon-caprolactones, the delta-valerolactones reacted further with the lipase delivering trans-esterified products and also acetylated alcohols, depending on the structural nature of the cyclopentanones, (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：61 / 66

页数：6

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