Crystal structure and thermal decomposition kinetics of a 2D coordination polymer of cadmium(II)

被引：2
|
作者：
Zhou, Ying-Xia [1 ]
Liu, Si-Yin [2 ]
Shen, Xiao-Qing [3 ]
Zhang, Hong-Yun [3 ]
Yu, Ya-Hui [3 ]
机构：
[1] Henan Agr Univ, Coll Sci, Zhengzhou 450002, Peoples R China
[2] Shangqiu Normal Coll, Dept Chem, Shangqiu 476000, Peoples R China
[3] Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Peoples R China
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2008年 / 61卷 / 20期
基金：
美国国家科学基金会;
关键词：
coordination polymer; cadmium(II); oxalate; thermal decomposition kinetics;
D O I：
10.1080/00958970802020665
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A 2D cadmium(II) coordination polymer with oxalate and 2,2'-bipyridine, [Cd-2(bpy)(ox)(2)(H2O)(2)]n nH(2)O, was synthesized and the single crystal structure was determined by X-ray crystallography. Thermal properties and the decomposition kinetics of the title complex were studied showing that the decomposition of this complex in N2 is a two-step process, A ->(F1) B ->(Fn) C. Kinetic parameters were obtained.
引用
收藏
页码：3237 / 3244
页数：8
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