Crystal structure and thermal decomposition kinetics of a 2D coordination polymer of cadmium(II)

被引：2
作者：
Zhou, Ying-Xia [1 ]
Liu, Si-Yin [2 ]
Shen, Xiao-Qing [3 ]
Zhang, Hong-Yun [3 ]
Yu, Ya-Hui [3 ]
机构：
[1] Henan Agr Univ, Coll Sci, Zhengzhou 450002, Peoples R China
[2] Shangqiu Normal Coll, Dept Chem, Shangqiu 476000, Peoples R China
[3] Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Peoples R China
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2008年 / 61卷 / 20期
基金：
美国国家科学基金会;
关键词：
coordination polymer; cadmium(II); oxalate; thermal decomposition kinetics;
D O I：
10.1080/00958970802020665
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A 2D cadmium(II) coordination polymer with oxalate and 2,2'-bipyridine, [Cd-2(bpy)(ox)(2)(H2O)(2)]n nH(2)O, was synthesized and the single crystal structure was determined by X-ray crystallography. Thermal properties and the decomposition kinetics of the title complex were studied showing that the decomposition of this complex in N2 is a two-step process, A ->(F1) B ->(Fn) C. Kinetic parameters were obtained.
引用
收藏
页码：3237 / 3244
页数：8
相关论文
共 25 条
  • [1] BAMFORD CH, 1980, COMPREHENSIVE CHEM K, V22, P57
  • [2] Inorganic crystal engineering using self-assembly of tailored building-blocks
    Blake, AJ
    Champness, NR
    Hubberstey, P
    Li, WS
    Withersby, MA
    Schröder, M
    [J]. COORDINATION CHEMISTRY REVIEWS, 1999, 183 : 117 - 138
  • [3] One-dimensional oxalato-bridged copper(II) complex possessing two structurally different metallic centres
    Castillo, O
    Luque, A
    Lloret, F
    Román, P
    [J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2001, 4 (07) : 350 - 353
  • [4] Synthesis, structure, and fluorescence of the novel cadmium(II)-trimesate coordination polymers with different coordination architectures
    Dai, JC
    Wu, XT
    Fu, ZY
    Cui, CP
    Hu, SM
    Du, WX
    Wu, LM
    Zhang, HH
    Sun, RO
    [J]. INORGANIC CHEMISTRY, 2002, 41 (06) : 1391 - 1396
  • [5] ELECTRONIC-PROPERTIES AND CRYSTAL-STRUCTURE OF AQUA(1,10-PHENANTHROLINE)-(OXALATO-O1O2) COPPER(II) MONOHYDRATE
    FABRETTI, AC
    FRANCHINI, G
    ZANNINI, P
    DIVAIRA, M
    [J]. INORGANICA CHIMICA ACTA-ARTICLES AND LETTERS, 1985, 105 (03): : 187 - 191
  • [6] Two new polymeric chains derived from exo-bidentate binaphthol derivatives
    Gong, YQ
    Zhou, YF
    Han, L
    Wang, RH
    Wu, BL
    Lou, BY
    Hong, MC
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 2005, 748 (1-3) : 195 - 199
  • [7] Syntheses, crystal structures and photoluminescence of two Cd(II) coordination polymers derived from a flexible bipyridyl ligand
    Gong, YQ
    Wang, RH
    Zhou, YF
    Yuan, DQ
    Hong, MC
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 2004, 705 (1-3) : 29 - 34
  • [8] Copper(II) complexes of 1,4,5,8,9,12-hexaazatriphenylene with oxalate, squarate, perchlorate as auxiliary ligands or counter ion
    Grove, H
    Sletten, J
    Julve, M
    Lloret, F
    Lezama, L
    Carranza, J
    Parsons, S
    Rillema, P
    [J]. JOURNAL OF MOLECULAR STRUCTURE, 2002, 606 (1-3) : 253 - 265
  • [9] Synthesis and crystal structures of two nickel coordination polymers generated from asymmetric malate ligand
    Guo, YQ
    Xiao, DR
    Wang, EB
    Lu, Y
    Lü, J
    Xu, XX
    Xu, L
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 2005, 178 (03) : 776 - 781
  • [10] Hagrman PJ, 1999, ANGEW CHEM INT EDIT, V38, P2639
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